Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 25, Problem 37DSP
Interpretation Introduction

Interpretation:

The carbon atoms involved in the carbon-carbon bond forming step in the given reactionare to be determined.

Concept introduction:

During the intramolecular aldol condensation, a slightly longer polyketide chain, a carbonyl tautomerizes to an enol.

This enol acts as a nucleophile and attacks a carbonyl carbon, forming a stable six membered ring.

This is the step in which a new carbon-carbon bond is formed.

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pressure (atm) 3 The pressure on a sample of pure X held at 47. °C and 0.88 atm is increased until the sample condenses. The pressure is then held constant and the temperature is decreased by 82. °C. On the phase diagram below draw a path that shows this set of changes. 0 0 200 temperature (K) 400 а
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