ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
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Chapter 25, Problem 55PP

(a)

Interpretation Introduction

Interpretation:

The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.

Concept introduction:

Ninhydrin react with primary amines to give a purple colored product.  This is a qualitative and quantitative test.  The aldehyde is obtained as by-product.  The general scheme can be shown as,

ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY, Chapter 25, Problem 55PP , additional homework tip  1

To draw : To identify the amino acids required to form the given aldehydes

(b)

Interpretation Introduction

Interpretation:

The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.

Concept introduction:

Ninhydrin react with primary amines to give a purple colored product.  This is a qualitative and quantitative test.  The aldehyde is obtained as by-product.  The general scheme can be shown as,

ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY, Chapter 25, Problem 55PP , additional homework tip  2

To draw : To identify the structure of  compound responsible for purple color.

(c)

Interpretation Introduction

Interpretation:

The amino acids required for obtaining the given aldehyde and the compound responsible for purple coloration need to be identified.

Concept introduction:

Ninhydrin react with primary amines to give a purple colored product.  This is a qualitative and quantitative test.  The aldehyde is obtained as by-product.  The purple coloration is seen due to compound that has more conjugated systems.  The more conjugation is present in the system the more colored the compound will be.  The general scheme can be shown as,

ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY, Chapter 25, Problem 55PP , additional homework tip  3

To draw : To identify the origin of the purple color.

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Chapter 25 Solutions

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