Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 2.5, Problem 19ATS
Interpretation Introduction
Interpretation:
The identification of lone pair in Amino acid has to be done.
Concept Introduction:
Lone pair:
A lone pair is given by a pair of outer most electrons that are not shared with another atom, otherwise called as non bonding pair. These are generally found in the valence shell of atom and are identified by Lewis structure. Pairs of electrons are considered as lone pairs when two electrons are paired and are not participated in
Delocalized lone pair:
The lone pair that participates in resonance is called as delocalized lone pair. The presence of lone pair affects the geometry of the atom.
Localized lone pair:
The lone pair that doesn’t participate in the resonance is called localized lone pair. The lone pair is not allylic to
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1. Identify the following alkenes as E or Z
NH₂
Br
2. Draw the structures based on the IUPAC names
(3R,4R)-3-bromo-4-fluoro-
1-hexene
(Z)-4-bromo-2-iodo-3-ethyl-
3-heptene
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3. For the following, predict all possible elimination product(s) and circle the major product.
HO
H₂SO4
Heat
80
F4
OH
H2SO4
Heat
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F5
F6
1
A
DII
4
F7
F8
F9
%
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5
6
7
* ∞
8
BAB
3
E
R
T
Y
U
9
F
D
G
H
J
K
O
A
F11
F10
Draw the major product of this reaction. Ignore inorganic
byproducts.
○
O
1. H₂O, pyridine
2. neutralizing work-up
a
N
W
X
人
P
Chapter 2 Solutions
Organic Chemistry
Ch. 2.1 - Prob. 1LTSCh. 2.1 - Prob. 1PTSCh. 2.1 - Prob. 2ATSCh. 2.1 - Prob. 3ATSCh. 2.1 - Prob. 4ATSCh. 2.2 - Prob. 2LTSCh. 2.2 - Prob. 5PTSCh. 2.2 - Prob. 6ATSCh. 2.2 - Prob. 7ATSCh. 2.2 - Prob. 3LTS
Ch. 2.2 - Prob. 8PTSCh. 2.2 - Prob. 9ATSCh. 2.2 - Prob. 10ATSCh. 2.3 - Prob. 11CCCh. 2.4 - Prob. 12CCCh. 2.4 - Prob. 13CCCh. 2.5 - Prob. 4LTSCh. 2.5 - Prob. 14PTSCh. 2.5 - Prob. 15ATSCh. 2.5 - Prob. 5LTSCh. 2.5 - Prob. 16PTSCh. 2.5 - Prob. 17ATSCh. 2.5 - Prob. 18ATSCh. 2.5 - Prob. 19ATSCh. 2.6 - Prob. 20CCCh. 2.8 - Prob. 6LTSCh. 2.8 - Prob. 21PTSCh. 2.8 - Prob. 22ATSCh. 2.9 - Prob. 7LTSCh. 2.9 - Prob. 23PTSCh. 2.9 - Prob. 24ATSCh. 2.10 - Prob. 25CCCh. 2.10 - Prob. 26CCCh. 2.10 - Prob. 27CCCh. 2.10 - Prob. 28CCCh. 2.10 - Prob. 29CCCh. 2.10 - Prob. 30CCCh. 2.10 - Prob. 31CCCh. 2.10 - Prob. 32CCCh. 2.11 - Prob. 8LTSCh. 2.11 - Prob. 33PTSCh. 2.11 - Prob. 34ATSCh. 2.11 - Prob. 35ATSCh. 2.12 - Prob. 9LTSCh. 2.12 - Prob. 36PTSCh. 2.12 - Prob. 37ATSCh. 2.12 - Prob. 38ATSCh. 2 - Prob. 39PPCh. 2 - Prob. 40PPCh. 2 - Prob. 41PPCh. 2 - Prob. 42PPCh. 2 - Prob. 43PPCh. 2 - Prob. 44PPCh. 2 - Prob. 45PPCh. 2 - Prob. 46PPCh. 2 - Prob. 47PPCh. 2 - Prob. 48PPCh. 2 - Prob. 49PPCh. 2 - Prob. 50PPCh. 2 - Prob. 51PPCh. 2 - Prob. 52PPCh. 2 - Prob. 53PPCh. 2 - Prob. 54PPCh. 2 - Prob. 55PPCh. 2 - Prob. 56PPCh. 2 - Prob. 57PPCh. 2 - Prob. 58PPCh. 2 - Prob. 59PPCh. 2 - Prob. 60PPCh. 2 - Prob. 61PPCh. 2 - Prob. 62PPCh. 2 - Prob. 65IPCh. 2 - Prob. 66IPCh. 2 - Prob. 67IP
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