Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 2.8, Problem 22ATS
Interpretation Introduction
Interpretation:
The curved arrow has to be draw to avoid the violation of curved arrow rules.
Concept Introduction:
Curved arrows:
The necessary tools to draw perfect resonance structure are curved arrows. Curved arrows don’t represent the flow of electrons. A tail and a head can be seen in curved arrow.
A head and tail of every arrow are to be drawn in the exact location. The tail represents where the electrons are originated, and the head represents the place where the electrons are going.
Rules for the curved arrow:
- 1) The breaking of single bond should be avoided.
- 2) The octet should never be exceeding for second row elements.
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
དྲ。
✗MgBr
?
O
CI
Will the first product that forms in this reaction
create a new C-C bond?
Yes
No
•
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
×
: ☐
X
Predict the major products of this organic reaction:
OH
NaBH4
H
?
CH3OH
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
☐ :
S
Predict the major products of this organic reaction:
1. LIAIHA
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
X
: ☐
Chapter 2 Solutions
Organic Chemistry
Ch. 2.1 - Prob. 1LTSCh. 2.1 - Prob. 1PTSCh. 2.1 - Prob. 2ATSCh. 2.1 - Prob. 3ATSCh. 2.1 - Prob. 4ATSCh. 2.2 - Prob. 2LTSCh. 2.2 - Prob. 5PTSCh. 2.2 - Prob. 6ATSCh. 2.2 - Prob. 7ATSCh. 2.2 - Prob. 3LTS
Ch. 2.2 - Prob. 8PTSCh. 2.2 - Prob. 9ATSCh. 2.2 - Prob. 10ATSCh. 2.3 - Prob. 11CCCh. 2.4 - Prob. 12CCCh. 2.4 - Prob. 13CCCh. 2.5 - Prob. 4LTSCh. 2.5 - Prob. 14PTSCh. 2.5 - Prob. 15ATSCh. 2.5 - Prob. 5LTSCh. 2.5 - Prob. 16PTSCh. 2.5 - Prob. 17ATSCh. 2.5 - Prob. 18ATSCh. 2.5 - Prob. 19ATSCh. 2.6 - Prob. 20CCCh. 2.8 - Prob. 6LTSCh. 2.8 - Prob. 21PTSCh. 2.8 - Prob. 22ATSCh. 2.9 - Prob. 7LTSCh. 2.9 - Prob. 23PTSCh. 2.9 - Prob. 24ATSCh. 2.10 - Prob. 25CCCh. 2.10 - Prob. 26CCCh. 2.10 - Prob. 27CCCh. 2.10 - Prob. 28CCCh. 2.10 - Prob. 29CCCh. 2.10 - Prob. 30CCCh. 2.10 - Prob. 31CCCh. 2.10 - Prob. 32CCCh. 2.11 - Prob. 8LTSCh. 2.11 - Prob. 33PTSCh. 2.11 - Prob. 34ATSCh. 2.11 - Prob. 35ATSCh. 2.12 - Prob. 9LTSCh. 2.12 - Prob. 36PTSCh. 2.12 - Prob. 37ATSCh. 2.12 - Prob. 38ATSCh. 2 - Prob. 39PPCh. 2 - Prob. 40PPCh. 2 - Prob. 41PPCh. 2 - Prob. 42PPCh. 2 - Prob. 43PPCh. 2 - Prob. 44PPCh. 2 - Prob. 45PPCh. 2 - Prob. 46PPCh. 2 - Prob. 47PPCh. 2 - Prob. 48PPCh. 2 - Prob. 49PPCh. 2 - Prob. 50PPCh. 2 - Prob. 51PPCh. 2 - Prob. 52PPCh. 2 - Prob. 53PPCh. 2 - Prob. 54PPCh. 2 - Prob. 55PPCh. 2 - Prob. 56PPCh. 2 - Prob. 57PPCh. 2 - Prob. 58PPCh. 2 - Prob. 59PPCh. 2 - Prob. 60PPCh. 2 - Prob. 61PPCh. 2 - Prob. 62PPCh. 2 - Prob. 65IPCh. 2 - Prob. 66IPCh. 2 - Prob. 67IP
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Similar questions
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
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