BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Chapter 25, Problem 17QP
Interpretation Introduction
Interpretation:
The
Concept introduction:
The molecular model of a chemical compound represents the three-dimensional arrangement of the atoms and the bonds between them. The atoms are denoted by spheres, which are connected by rods that represent the bonds. Compounds contain
All atoms have a different color, such as carbon is black, nitrogen is dark blue, oxygen is red, and hydrogen is white.
The compound PABA stands for para-aminobenzoic acid, that is, an active
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 25 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 25.1 - Prob. 1PPACh. 25.1 - Prob. 1PPBCh. 25.1 - Prob. 1PPCCh. 25.2 - Prob. 1PPACh. 25.2 - Prob. 1PPBCh. 25.2 - Prob. 1PPCCh. 25.2 - Prob. 1CPCh. 25.2 - Prob. 2CPCh. 25.2 - Identify the name of the following compound: a)...Ch. 25.2 - Prob. 4CP
Ch. 25.2 - Prob. 5CPCh. 25.2 - Prob. 6CPCh. 25.3 - Prob. 1PPACh. 25.3 - Prob. 1PPBCh. 25.3 - Prob. 1PPCCh. 25.3 - Prob. 1CPCh. 25.3 - Prob. 2CPCh. 25.3 - Prob. 3CPCh. 25.3 - Prob. 4CPCh. 25.4 - Prob. 1PPACh. 25.4 - Prob. 1PPBCh. 25.4 - Prob. 1PPCCh. 25.5 - Prob. 1PPACh. 25.5 - Prob. 1PPBCh. 25.5 - Prob. 1PPCCh. 25.5 - Prob. 1CPCh. 25.5 - Prob. 2CPCh. 25 - Prob. 1QPCh. 25 - 25.2 Why was Wöhler’s synthesis of urea so...Ch. 25 - Prob. 3QPCh. 25 - Prob. 4QPCh. 25 - Prob. 5QPCh. 25 - Prob. 6QPCh. 25 - Prob. 7QPCh. 25 - Prob. 8QPCh. 25 - Prob. 9QPCh. 25 - Prob. 10QPCh. 25 - Prob. 11QPCh. 25 - Prob. 12QPCh. 25 - Prob. 13QPCh. 25 - Prob. 14QPCh. 25 - Prob. 15QPCh. 25 - Identify the functional groups in the...Ch. 25 - Prob. 17QPCh. 25 - Prob. 18QPCh. 25 - Prob. 19QPCh. 25 - Prob. 20QPCh. 25 - Prob. 21QPCh. 25 - Prob. 22QPCh. 25 - Prob. 23QPCh. 25 - Prob. 24QPCh. 25 - Prob. 25QPCh. 25 - Prob. 26QPCh. 25 - Prob. 27QPCh. 25 - Prob. 28QPCh. 25 - Prob. 29QPCh. 25 - Prob. 30QPCh. 25 - Prob. 31QPCh. 25 - Prob. 32QPCh. 25 - Prob. 33QPCh. 25 - Prob. 34QPCh. 25 - Prob. 35QPCh. 25 - Prob. 36QPCh. 25 - Prob. 37QPCh. 25 - Prob. 38QPCh. 25 - Prob. 39QPCh. 25 - Prob. 40QPCh. 25 - Prob. 41QPCh. 25 - Prob. 42QPCh. 25 - Prob. 43QPCh. 25 - Prob. 44QPCh. 25 - Prob. 45QPCh. 25 - Prob. 46QPCh. 25 - Prob. 47QPCh. 25 - Prob. 48QPCh. 25 - Prob. 49QPCh. 25 - Prob. 50QPCh. 25 - Prob. 51QPCh. 25 - Prob. 52QPCh. 25 - Prob. 53QPCh. 25 - Prob. 54QPCh. 25 - Prob. 55QPCh. 25 - Prob. 56QPCh. 25 - Prob. 57QPCh. 25 - Prob. 58QPCh. 25 - Prob. 59QPCh. 25 - Prob. 60QPCh. 25 - Prob. 61QPCh. 25 - Prob. 62QPCh. 25 - Prob. 63QPCh. 25 - Prob. 64QPCh. 25 - Prob. 65QPCh. 25 - Prob. 66QPCh. 25 - Prob. 67QPCh. 25 - Prob. 68QPCh. 25 - Prob. 69QPCh. 25 - Prob. 70QPCh. 25 - Prob. 71QPCh. 25 - Prob. 72QPCh. 25 - Prob. 73QPCh. 25 - Prob. 74QPCh. 25 - Prob. 75QPCh. 25 - Prob. 76QPCh. 25 - Prob. 77APCh. 25 - Prob. 78APCh. 25 - Prob. 79APCh. 25 - Prob. 80APCh. 25 - Prob. 81APCh. 25 - Match each molecular model with the correct...Ch. 25 - Prob. 83APCh. 25 - Prob. 84APCh. 25 - Prob. 85APCh. 25 - Prob. 86APCh. 25 - Prob. 87APCh. 25 - Prob. 88APCh. 25 - Prob. 89APCh. 25 - Prob. 90APCh. 25 - Prob. 91APCh. 25 - Prob. 92APCh. 25 - Prob. 93APCh. 25 - Prob. 94APCh. 25 - Prob. 95APCh. 25 - Prob. 96APCh. 25 - Prob. 97APCh. 25 - Prob. 98APCh. 25 - Prob. 99APCh. 25 - Prob. 100APCh. 25 - All alkanes give off heat when burned in air. Such...Ch. 25 - Prob. 102APCh. 25 - Prob. 1SEPPCh. 25 - Prob. 2SEPPCh. 25 - Prob. 3SEPPCh. 25 - Prob. 4SEPP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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