Concept explainers
Interpretation:
The structural formulas for given compounds are to be written.
Concept introduction:
The longest chain is termed as the parent chain, which is then numbered from the end that the substituted carbons get a lower number. The name and number of substituents are then prefixed to the name of the parent chain.
In chemical nomenclature, the
The parent chain is the longest continuous chain of carbon atoms.
The parent chain is numbered from that end which is closest to the substituent.
If the same substituent occurs more than once, the location of each point on which the substituent occurs is given.
If there are two or more different substituents they are listed in alphabetical order using the base name
The name of the
A structural formula is the formula thatprovides an insight into the structure of the compound. It shows all the substituents and
The structure can be easily written from the systematic name. The parent chain is at first drawn and numbered from any end.
Thereafter, the name is written thatincludes the name and the number of substituents. The substituents are written with their number in alphabetical order followed by the name of the parent chain and the functional group as a suffix.
The suffix –olis used for the alcohol group.
The suffix –al is used for the aldehyde group.
The suffix –one is used for the ketone group.
The –e ending of an alkane is replaced by –amine for amine functional group.
The suffix amide is then added for the amide group.
The suffix -oate is used for the ester.
Functional groups are specific substituent within the molecules that are responsible for the characteristic
Esters are the organic compounds thatcontain
Alcohols are the organic compounds thatcontain
Amides are the organic compounds thatcontain
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Chapter 25 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
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- Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10arrow_forwardQ: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCCarrow_forwardNonearrow_forward
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