Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 24.8, Problem 8P
Interpretation Introduction

Interpretation:

The percent of α- and β-D-mannopyranose isomer at equilibrium has to be calculated.

Concept introduction:

A mixture that has an equal amount of enantiomers is commonly known as a racemic mixture. Enantiomers have non-superimposable mirror images of one other and therefore; they rotate the plane of polarized light in the opposite but equal direction. The racemic mixture is optically inactive in nature.

The property of a chiral compound in which the compound changes the orientation of the monochromatic light is known as specific rotation. This change in orientation takes place per unit distance-concentration of the product.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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