Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 24, Problem 46DSP
Interpretation Introduction

Interpretation:

The possible structures for (+)-mannose and (+)-glucose from the given pairs are to be chosen.

Concept introduction:

In chain extension reactions of aldoses, the carbon atom is added to the aldehyde group and forms sugars with one more carbon atom that the substrate.

Molecules containing two identical chiral centers can be achiral.

The stereo centers in the original sugar remain unaffected in chain extension reactions.

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H 1) OsO4, pyridine 2) Na2SO3 or NaHSO3 in H₂O 2 products
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