From the given starting material the complete synthesis of the given product is to be written. Concept introduction: The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides. The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose. The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

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Answer 1

Question

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

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Answer 2

Question

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Expert Solution & Answer

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Answer 4

Question

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Expert Solution & Answer

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Answer 5

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Answer 6

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Answer 7

Chapter 24, Problem 43P

Interpretation Introduction

Interpretation:

From the given starting material the complete synthesis of the given product is to be written.

Concept introduction:

The hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides.

The triphenylmethyl chloride reacts selectively with primary alcohols C-6 in hexose.

The ether formed at C-6 in hexose by the reaction of triphenylmethyl chloride can be selectively removed by mild acid hydrolysis without disturbing methyl glycoside.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 24.2 - Prob. 1P Ch. 24.3 - Problem 24.2 Which aldotetrose in the structure...Ch. 24.4 - Prob. 3P Ch. 24.4 - Prob. 4P Ch. 24.6 - Prob. 5P Ch. 24.6 - Prob. 6P Ch. 24.7 - Prob. 7P Ch. 24.8 - Prob. 8P Ch. 24.8 - Prob. 9P Ch. 24.9 - Prob. 10P

Solution Summary: The author explains that the hydroxyl groups of carbohydrates can be alkylated on reaction with benzyl chlorides. The ether formed at C-6 in hexose

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Chapter 24 Solutions