EBK ORGANIC CHEMISTRY
7th Edition
ISBN: 9780133556186
Author: Bruice
Publisher: VST
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Question
Chapter 24.5, Problem 12P
(a)
Interpretation Introduction
Interpretation:
Formation of product of amino acid when
Concept introduction:
In an enzyme – catalysed reaction that requires coenzymes
(b)
Interpretation Introduction
Interpretation:
Formation of product of amino acid when
Concept introduction:
In an enzyme – catalysed reaction that requires coenzymes, a group bonded to one carbon changes places with a hydrogen bonded to an adjacent carbon.
Expert Solution & Answer
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Students have asked these similar questions
Give the major product of the following reaction.
excess
1. OH, H₂O
1.OH
H
CH3CH2CH21
H
2. A.-H₂O
Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and
Advanced Template toolbars. The single bond is active by default.
2. Use Hess's law to calculate the AH
(in kJ) for:
rxn
CIF(g) + F2(g) →
CIF 3 (1)
using the following information:
2CIF(g) + O2(g) →
Cl₂O(g) + OF 2(g)
AH = 167.5 kJ
ΔΗ
2F2 (g) + O2(g) → 2 OF 2(g)
2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g)
о
=
= -43.5 kJ
AH = 394.1kJ
ci
Draw the major product(s) of the following reactions: (3 pts)
CH3
HNO3/H2SO4
HNO3/ H2SO4
OCH3
(1 pts)
Chapter 24 Solutions
EBK ORGANIC CHEMISTRY
Ch. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.2 - How many conjugated double bonds are there in a....Ch. 24.2 - Instead of adding to the 4a position and...Ch. 24.2 - Prob. 7PCh. 24.3 - Prob. 8PCh. 24.3 - Acetolactate synthase is another TPP-requiring...Ch. 24.3 - Acetolactate synthase transfers the acyl group of...Ch. 24.5 - Prob. 12PCh. 24.5 - The enzyme that catalyzes the C C bond cleavage...
Ch. 24.5 - Propose a mechanism for the ,-elimination reaction...Ch. 24.5 - Which compound is more easily decarboxylated?Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.6 - Ethanolamine ammonia lyase, a coenzyme...Ch. 24.6 - Prob. 19PCh. 24.7 - How do the structure of tetrahydrofolate and...Ch. 24.7 - What is the source of the methyl group in...Ch. 24.8 - Thiols such as ethanethiol and propanethiol can be...Ch. 24 - How does the metal ion in carboxypeptidase A...Ch. 24 - Prob. 23PCh. 24 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - S-Adenosylmethionine (SAM) is formed from the...Ch. 24 - Prob. 27PCh. 24 - What acyl groups have we seen transferred by...Ch. 24 - Propose a mechanism for the following reaction:Ch. 24 - When transaminated, the three branched-chain amino...Ch. 24 - Draw the products of the following reaction, where...Ch. 24 - When UMP is dissolved in T2O, exchange of T for H...Ch. 24 - Dehydratase is a PLP-requiring enzyme that...Ch. 24 - In addition to the reaction mentioned in Section...Ch. 24 - PLP can catalyze both ,-elimination reactions...Ch. 24 - The glycine cleavage system is a group of four...Ch. 24 - Prob. 37PCh. 24 - FADH2 reduces , -unsaturated thioesters to...
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- What is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forwardCheck all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forward
- Consider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forwardFor each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forward
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