EBK ORGANIC CHEMISTRY
7th Edition
ISBN: 9780133556186
Author: Bruice
Publisher: VST
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Textbook Question
Chapter 24, Problem 28P
What acyl groups have we seen transferred by reactions thiamine pyrophosphate as a coenzymes? (Hint: See problems 9, 10, 11, 27, and 28.)
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3.
An unknown element, X, combines with chlorine to give a substance with the formula
XC14. A chlorine analysis of the substance indicates that it contains 83.47% chlorine by mass.
What element is X and what is the formula of this compound?
(Hint: to identify an element or compound, identify its molar mass. Remember that Molar Mass
= (grams A)/(moles A). Solve for each individually and then divide them to find molar mass.)
1.
When hydrogen sulfide (H2S, MM = 34.08 g/mol) gas is bubbled into a solution of
sodium hydroxide (NaOH, 40.00 g/mol), sodium sulfide (Na2S, 78.04 g/mol) and water (18.02
g/mol) are produced according to the balanced chemical equation shown below?
H2S 2 NaOH --> Na2S 2 H₂O
(a) Assuming the reaction goes to completion, how many grams of sodium sulfide are formed if
2.50g of hydrogen sulfide is bubbled into a solution containing 1.85g of NaOH? (20 pts)
(b) Which reactant and how much of it remains after the reaction has been completed? (15 pts)
(c) If only 0.400g of sodium sulfide was recovered, what is the percent yield of this reaction (5
pts)
Chapter 24 Solutions
EBK ORGANIC CHEMISTRY
Ch. 24.1 - Prob. 2PCh. 24.1 - Prob. 3PCh. 24.2 - How many conjugated double bonds are there in a....Ch. 24.2 - Instead of adding to the 4a position and...Ch. 24.2 - Prob. 7PCh. 24.3 - Prob. 8PCh. 24.3 - Acetolactate synthase is another TPP-requiring...Ch. 24.3 - Acetolactate synthase transfers the acyl group of...Ch. 24.5 - Prob. 12PCh. 24.5 - The enzyme that catalyzes the C C bond cleavage...
Ch. 24.5 - Propose a mechanism for the ,-elimination reaction...Ch. 24.5 - Which compound is more easily decarboxylated?Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.5 - Explain why the ability of PLP to catalyze an...Ch. 24.6 - Ethanolamine ammonia lyase, a coenzyme...Ch. 24.6 - Prob. 19PCh. 24.7 - How do the structure of tetrahydrofolate and...Ch. 24.7 - What is the source of the methyl group in...Ch. 24.8 - Thiols such as ethanethiol and propanethiol can be...Ch. 24 - How does the metal ion in carboxypeptidase A...Ch. 24 - Prob. 23PCh. 24 - Prob. 24PCh. 24 - Prob. 25PCh. 24 - S-Adenosylmethionine (SAM) is formed from the...Ch. 24 - Prob. 27PCh. 24 - What acyl groups have we seen transferred by...Ch. 24 - Propose a mechanism for the following reaction:Ch. 24 - When transaminated, the three branched-chain amino...Ch. 24 - Draw the products of the following reaction, where...Ch. 24 - When UMP is dissolved in T2O, exchange of T for H...Ch. 24 - Dehydratase is a PLP-requiring enzyme that...Ch. 24 - In addition to the reaction mentioned in Section...Ch. 24 - PLP can catalyze both ,-elimination reactions...Ch. 24 - The glycine cleavage system is a group of four...Ch. 24 - Prob. 37PCh. 24 - FADH2 reduces , -unsaturated thioesters to...
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