The coenzyme transfers an acyl group from one substrate to another should be determined. Concept introduction: Cofactors that are organic molecule are called coenzymes; Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts. Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

Question

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Answer 1

Question

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

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Answer 3

Question

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Expert Solution & Answer

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Answer 4

Question

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Expert Solution & Answer

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Answer 5

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 6

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

Answer 7

Chapter 24, Problem 23P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 20

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 21

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Answer 22

Expert Solution & Answer

Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.2 - How many conjugated double bonds are there in a....Ch. 24.2 - Instead of adding to the 4a position and...Ch. 24.2 - Prob. 7P Ch. 24.3 - Prob. 8P Ch. 24.3 - Acetolactate synthase is another TPP-requiring...Ch. 24.3 - Acetolactate synthase transfers the acyl group of...Ch. 24.5 - Prob. 12P Ch. 24.5 - The enzyme that catalyzes the C C bond cleavage...

Solution Summary: The author explains that the coenzyme transfers an acyl group from one substrate to another. The reaction necessary for proper blood clotting is catalysed by vitamin KH2.

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Chapter 24 Solutions