(a) Interpretation: The compounds needed to carry out Step [1] are to be stated. Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α − carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester . The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Question

Want to see the full answer?

Answer 1

Question

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Q3: Draw the Lewis structures for nitromethane (CH3NO2) and methyl nitrite (CH3ONO). Draw at least two resonance forms for each. Determine which form for each is the major resonance contributor. Page 1 of 4 Chem 0310 Organic Chemistry 1 Recitations Q4: Draw the Lewis structures for the cyanate ion (OCN‍) and the fulminate ion (CNO-). Draw all possible resonance structures for each. Determine which form for each is the major resonance contributor.

Metallic clusters and nanomaterials.

Metal clusters: photochemical properties of special relevance in solar energy conversion

Answer 2

Question

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 6

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 7

Chapter 24, Problem 24.68P

Interpretation Introduction

(a)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compounds needed to carry out Step [1] are to be stated.

Concept introduction:

In crossed claisen condensation reaction, the base abstracts the acidic proton from α− carbon atom of an ester to form enolate. This enolate reacts with carbonyl group of other ester that leads to the formation of a β-keto ester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The detailed mechanism for step [3] is to be drawn.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The detailed mechanism for step [4] is to be drawn. The reason as to why the product formed is unusual is to be stated.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The reason behind the unnecessary addition and removal of formyl group is to be predicted.

Concept introduction:

When only one carbonyl component has an alpha hydrogen atom, then a cross aldol reaction will occur. There will be formation of only one product. The yield of single cross aldol condensation reaction is enhanced if the electrophilic carbonyl compound is relatively unhindered.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 19

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 24 - Acid-catalyzed dehydration of hydroxy carbonyl...Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Prob. 24.7P Ch. 24 - Problem 24.8 Draw the products formed in the...Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that the compounds needed to carry out Step 1 are HCOOEt, NaOEt.

Want to see the full answer?

Chapter 24 Solutions