The structure of the alkane cyclopentane has to be predicted. Concept introduction: IUPAC Nomenclature of cycloalkanes: The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’. The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain. While numbering the longest chain, the substituent should get least possible number. Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Question

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Answer 1

Question

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.

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Answer 2

Question

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

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Answer 3

Question

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

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Answer 4

Question

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

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Answer 5

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

Answer 6

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

Answer 7

Chapter 24, Problem 24.59QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 8

a)

Expert Solution

Explanation of Solution

Given name: cyclopentane

Predict the longest continuous chain of carbon atoms:

The parent name is CYCLOPENTANE represent the continuous ring of carbon atoms contains five carbons. The Suffix ‘ane’ represents the structure contains only single bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 1

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 2

Answer 9

a)

Expert Solution

Answer 10

a)

Expert Solution

Answer 11

Expert Solution

Answer 12

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

Answer 13

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

Answer 14

b)

Expert Solution

Explanation of Solution

Given name: cis-2-butene

Predict the longest continuous chain of carbon atoms:

The parent name is BUTENE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘ene’ represents presence of double bond at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 4

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms. The term ‘cis-’ indicates two hydrogen atoms are located adjacent to each other on same side.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 5

Answer 15

b)

Expert Solution

Answer 16

b)

Expert Solution

Answer 17

Expert Solution

Answer 18

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

Answer 19

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 20

c)

Expert Solution

Explanation of Solution

Given name: 2-hexanol

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 6

The parent name is HEXANOL represent the longest chain of carbon atoms contains six carbons. The Suffix ‘ol’ represents presence of hydroxy group –OH at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 7

The prefix ‘2-‘represent the presence of hydroxy group at C-2.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 8

Answer 21

c)

Expert Solution

Answer 22

c)

Expert Solution

Answer 23

Expert Solution

Answer 24

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

Answer 25

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

Answer 26

d)

Expert Solution

Explanation of Solution

Given name: 1,4-dibromobenzene

Predict the parent structure:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 10

The parent name is BENZENE represent the continuous ring of carbon atoms contains six carbons with alternative double bonds.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 11

The prefix ‘1, 4-dibromo’ indicates the presence of two identical bromine atom located at C-1 and C-4.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 12

Answer 27

d)

Expert Solution

Answer 28

d)

Expert Solution

Answer 29

Expert Solution

Answer 30

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15

Answer 31

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 32

e)

Expert Solution

Explanation of Solution

Given name: 2-butyne

Predict the longest continuous chain of carbon atoms:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 13

The parent name is BUTYNE represent the longest chain of carbon atoms contains four carbons. The Suffix ‘yne’ represents the structure contains only one triple bonds at C-2.

Predict substituents and its location:

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 14

No prefix available before the parent name pentane, thus, the structure has no substituents located at any carbon atoms.

Therefore, the structure is

Chemistry, Chapter 24, Problem 24.59QP , additional homework tip 15