Chemistry
Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 24, Problem 24.28QP

a)

Interpretation Introduction

Interpretation:

The structure for trans-2-pentene has to be drawn.

Concept introduction:

IUPAC Nomenclature:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.28QP , additional homework tip  1

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

b)

Interpretation Introduction

Interpretation:

The structure for 2-ethyl-1-butene has to be drawn.

Concept introduction:

IUPAC Nomenclature:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

c)

Interpretation Introduction

Interpretation:

The structure for 4-ethyl-trans-2-heptene has to be drawn.

Concept introduction:

IUPAC Nomenclature:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.

Chemistry, Chapter 24, Problem 24.28QP , additional homework tip  2

Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.

d)

Interpretation Introduction

Interpretation:

The structure for 3-phenyl-butyne has to be drawn.

Concept introduction:

IUPAC Nomenclature:

  • The longest continuous chain of carbon atoms is identified.
  • The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
  • While numbering the longest chain, the substituent should get least possible number.
  • Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Chapter 24 Solutions

Chemistry

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