(a) Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using − OH , H 2 O is to be drawn. Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry . In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 1

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Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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What carbonyl starting materials are needed to prepare each compound using a directed aldol reaction?

Use the malonic ester synthesis to prepare each carboxylic acid.

Convert each compound to its enol or keto tautomer. i CH3 CH3 Draw the aldol product formed from each compound. CH,CHO a. a. a. CHO b. b. b. (CH3)3CCH,CHO OH Which carbonyl compounds do not undergo an aldol reaction when treated with "OH in H₂O? C. (CH3)3C An ortho ester C. i i CH3 CH3 d. d. Draw the products formed in each crossed aldol reaction. a. CH,CH,CH,CHO and CHz=0 C. CH₂CHO and b. CH₂COCH3 and CH₂=O (CH3)3C CH3 e. Problem 19.12 How do you account for the following differences in ease of hydrolysis? (a) RC(OR), » RCH(OR')₂ » RCH₂OR' An acetal An ether CHO (b) R₂C(OR)₂ > RCH(OR')₂ > H₂C(OR')2

Answer 2

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 3

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 4

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 5

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 6

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 7

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 12

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Answer 14

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Answer 15

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Problem 24.7 Draw the products formed in each...Ch. 24 - Problem 24.8 Draw the products formed in the...Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that aldol reaction is the condensation reaction of the organic chemistry.

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Chapter 24 Solutions