Interpretation:
The observation, when the unsymmetrical
Concept introduction:
The enamine obtained from an unsymmetrical ketone will be stable only if it is free from steric strain. A strained unsymmetrical ketone will be unstable.
To explain:
The observation, when the unsymmetrical ketone, 2-methylcyclohexenone is converted into an enamine the sole product is the one with the double bond opposite to the methyl substituted carbon while the other possible enamine with methyl on the carbon in double bond is not formed.
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Chapter 23 Solutions
ORGANIC CHEMISTRY W/OWL
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