a) Interpretation: The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given. Concept introduction: Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor. To give: The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Don't used Ai solution and don't used hand raiting

Circle the letter next to the most appropriate response. 1) Which is likely to be the least soluble with water? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 2) Which is likely to be the most soluble in 3,4-dimethyloctane? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 3) When ammonium nitrate is dissolved in water, the solution: a) gets warmer. b) gets colder. c) stays the same temperature. d) is none of the above because potassium nitrate is insoluble.

None

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Answer 6

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Answer 7

Chapter 23.10, Problem 17P

Interpretation Introduction

a)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated acceptor.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with malonic ester, a nucleophilic donor.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown is to be given.

Concept introduction:

Michael reaction involves the conjugate addition of a stable enolate ion derived from a β-ketoesters or β- diketones or β- ketonitriles or malonic esters (donors) to an unhindered Î±,β- unsaturated ketones or aldehydes or esters or thioesters or nitriles or amides or nitro compounds (acceptors). The enolate ion from the donor attacks the double bond in acceptor. A new bond is formed between the Î±-carbon of the donor and the β- carbon of the unsaturated ester.

To give:

The product obtained in the base catalyzed Michael reaction of 3-buten-2-one with the β- keto ester, a nucleophilic donor shown.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 23.1 - Prob. 1P Ch. 23.1 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.3 - Prob. 4P Ch. 23.4 - Prob. 5P Ch. 23.4 - 1-Butanol is prepared commercially by a route that...Ch. 23.4 - Prob. 7P Ch. 23.5 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - What product would you Expect to obtain from base...

Want to see the full answer?

Chapter 23 Solutions