The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen is to be explained. Concept introduction: Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule. To explain: The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen.

Question

Consider the following Figure 2 and two atoms that are initially an infinite distance apart, x =00, at which point the potential energy of the system is U = 0. If they are brought together to x = x, the potential energy is related to the total force P by dU dx = P Given this, qualitatively sketch the variation of U with x. What happens at x=x? What is the significance of x = x, in terms of the potential energy? 0 P, Force 19 Attraction Total Repulsion x, Distance Figure 2. Variation with distance of the attractive, repulsive, and total forces between atoms. The slope dP/dx at the equilibrium spacing xe is proportional to the elastic modulus E; the stress σb, corresponding to the peak in total force, is the theoretical cohesive strength.

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 54AP

Interpretation Introduction

Interpretation:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen is to be explained.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To explain:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen.

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Consider the following Figure 2 and two atoms that are initially an infinite distance apart, x =00, at which point the potential energy of the system is U = 0. If they are brought together to x = x, the potential energy is related to the total force P by dU dx = P Given this, qualitatively sketch the variation of U with x. What happens at x=x? What is the significance of x = x, in terms of the potential energy? 0 P, Force 19 Attraction Total Repulsion x, Distance Figure 2. Variation with distance of the attractive, repulsive, and total forces between atoms. The slope dP/dx at the equilibrium spacing xe is proportional to the elastic modulus E; the stress σb, corresponding to the peak in total force, is the theoretical cohesive strength.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 54AP

Interpretation Introduction

Interpretation:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen is to be explained.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To explain:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen.

Expert Solution & Answer

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Check out sample textbook solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 54AP

Interpretation Introduction

Interpretation:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen is to be explained.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To explain:

The fact that 2, 2, 6-trimethylcyclohexanone yields no detectable aldol product even though it has an acidic α-hydrogen.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 23.SE, Problem 54AP

Interpretation Introduction