Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Chapter 23.6, Problem 17PTS
Interpretation Introduction

Interpretation:

The structure for boronic ester A and the coupled product B in given reaction sequence should be identified.

Concept Introduction:

Suzuki reaction: It involves coupling of an aryl, a benzyl or vinyl halide with organoborane in presence of Pd(PPh3)4.

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36. Give the major product(s) of each of the following reactions. Aqueous work-up steps (when necessary) have been omitted. a. CH3CH=CHCH3 b. CH3CH2CH2CCH3 H,PO₂, H₂O, A (Hint: See Section 2-2.) 1. LIAIH. (CH,CH,),O 2. H', H₂O H NaBH, CH,CH₂OH d. Br LIAIH. (CH,CH,)₂O f. CH3 NaBH, CH,CH,OH (CH3)2CH H NaBH, CH,CH₂OH H
Predict the major products of this reaction: + H excess NaOH Δ ? Note that the second reactant is used in excess, that is, there is much more of the second reactant than the first. If there won't be any products, just check the box under the drawing area instead.
An organic chemistry Teaching Assistant (TA) suggested in your last discussion section that there is only one major organic product of the following reaction and that this reaction builds a ring. If the TA is right, draw the product in the drawing area below. If the TA is wrong, just check the box below the drawing area. 1. NaOMe CH3O N. OCH3 ? 2. H3O+

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Organic Chemistry

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