Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
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Chapter 23, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The structures for products A and B in given reaction should be identified.

Concept Introduction:

Simmons–Smith reaction: It involves reaction of alkenes with organozinc reagent namely ICH2ZnI which results in formation of three–membered ring in product. This is a concerted reaction in which the configuration of starting alkene is preserved.

(b)

Interpretation Introduction

Interpretation:

The relationship between the two products A and B obtained from given reaction should be identified.

Concept Introduction:

Simmons–Smith reaction: It involves reaction of alkenes with organozinc reagent namely ICH2ZnI which results in formation of three–membered ring in product. This is a concerted reaction in which the configuration of starting alkene is preserved.

Diastereomers = The chiral centers of two compounds give opposite configuration. These compounds do not have mirror images.

(c)

Interpretation Introduction

Interpretation:

From the two obtained products, predominate product should be identified.

Concept Introduction:

Simmons–Smith reaction: It involves reaction of alkenes with organozinc reagent namely ICH2ZnI which results in formation of three–membered ring in product. This is a concerted reaction in which the configuration of starting alkene is preserved.

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Chapter 23 Solutions

Organic Chemistry

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