
Concept explainers
(a)
Interpretation:
The complete electron dot structure of given alcohol needs to be drawn and the molecular formula of the
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.
(b)
Interpretation:
The complete electron dot structure of given
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.
(c)
Interpretation:
The complete electron dot structure of given cyclic amine needs to be drawn and the molecular formula of the alkane with cyclic amine group needs to be determined.
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.
(d)
Interpretation:
The complete electron dot structure of the given ether needs to be drawn and the molecular formula of the alkane with ether group needs to be determined.
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.
(e)
Interpretation:
The complete electron dot structure of given
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.
(f)
Interpretation:
The complete electron dot structure of the given
Concept introduction:
The line drawing is a chemical structure in which carbon and hydrogen molecules are not drawn. In these types of structures, lines are used to draw structure representing molecules. In the electron dot structure, the lone pair of electrons are represented as two dots on the respective symbol of the atom.
A molecular formula is a chemical formula that tells the total number of atoms of each element in a molecule.

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Chapter 23 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwarda. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forward
- Draw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forwardConsider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forwardNH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forward
- Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forwardA 2-step reaction has the following mechanism: | 1. (fast) R2 R+R 2. (slow) R+Q K₂ P k_1 What series does it have? (A). v= - = (k + k1 − k-1)[R2][Q] (B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q] (C). v=k₂[R]²[Q]² (D). v = k[R₂]1/2[Q]arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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