Synthesis of 1-hexanamine has to be proposed from a bromoalkane of six carbon atoms. Concept introduction: Preparation of primary amines : It can be prepared in greater yield by treating a haloalkane with strong nucleophile like potassium azide or sodium azide and followed by reduction in presence of L i A l H 4 to form the corresponding amine. Reduction: If electrons are gained to a species or hydrogen atoms are added to a species or oxygen atom gets removed from a species during a chemical reaction is known as reduction. In certain reaction, L i A l H 4 (Lithium aluminium hydride) is used as a reducing agent.

Question

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Answer 1

Question

Chapter 23, Problem 23.33P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 1-hexanamine has to be proposed from a bromoalkane of six carbon atoms.

Concept introduction:

Preparation of primary amines:

It can be prepared in greater yield by treating a haloalkane with strong nucleophile like potassium azide or sodium azide and followed by reduction in presence of LiAlH4 to form the corresponding amine.

Reduction: If electrons are gained to a species or hydrogen atoms are added to a species or oxygen atom gets removed from a species during a chemical reaction is known as reduction. In certain reaction, LiAlH4 (Lithium aluminium hydride) is used as a reducing agent.

(a)

Interpretation Introduction

Interpretation:

Synthesis of 1-hexanamine has to be proposed from a bromoalkane of five carbon atoms.

Concept introduction:

Formation of nitrile:

A haloalkane reacts with potassium cyanide (KCN) to form the corresponding nitrile.

RCH2Br + KCN → RCH2CN+ KBr

Reduction: If electrons are gained to a species or hydrogen atoms are added to a species or oxygen atom gets removed from a species during a chemical reaction is known as reduction. In certain reaction, LiAlH4 (Lithium aluminium hydride) is used as a reducing agent.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे