ORGANIC CHEMISTRY (LL) W/ACCESS
ORGANIC CHEMISTRY (LL) W/ACCESS
4th Edition
ISBN: 9781119856122
Author: Klein
Publisher: WILEY
Question
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Chapter 22.4, Problem 10CC

(a)

Interpretation Introduction

Interpretation: The structures of an alkyl halide or carboxylic acid that serve as a precursor in the preparation of the given amines have to be drawn

Concept Introduction:

When sodium cyanide is allowed to react with alkyl halide, halide group is replaced by cyanide group via SN2 nucleophilic substitution reaction.  The cyanide group on treatment with lithium aluminum hydride which is a strong reducing agent, it reduces the cyanide group into methylene primary amine.  There is a single carbon skeleton increment in the given compound through this process.

To find: Draw the structure of an alkyl halide that serve as a precursor in the preparation of the given amine (a)

Do the SN2 nucleophilic substitution reaction

ORGANIC CHEMISTRY (LL) W/ACCESS, Chapter 22.4, Problem 10CC , additional homework tip  1

(b)

Interpretation Introduction

Interpretation: The structures of an alkyl halide or carboxylic acid that serve as a precursor in the preparation of the given amines have to be drawn

Concept Introduction:

When sodium cyanide is allowed to react with alkyl halide, halide group is replaced by cyanide group via SN2 nucleophilic substitution reaction.  The cyanide group on treatment with lithium aluminum hydride which is a strong reducing agent, it reduces the cyanide group into methylene primary amine.  There is a single carbon skeleton increment in the given compound through this process.

To find: Draw the structure of an alkyl halide that serve as a precursor in the preparation of the given amine (b)

Do the SN2 nucleophilic substitution reaction

ORGANIC CHEMISTRY (LL) W/ACCESS, Chapter 22.4, Problem 10CC , additional homework tip  2

(c)

Interpretation Introduction

Interpretation: The structures of an alkyl halide or carboxylic acid that serve as a precursor in the preparation of the given amines have to be drawn

Concept Introduction:

When sodium cyanide is allowed to react with alkyl halide, halide group is replaced by cyanide group via SN2 nucleophilic substitution reaction.  The cyanide group on treatment with lithium aluminum hydride which is a strong reducing agent, it reduces the cyanide group into methylene primary amine.  There is a single carbon skeleton increment in the given compound through this process.

To find: Draw the structure of an alkyl halide that serve as a precursor in the preparation of the given amine (c)

Do the SN2 nucleophilic substitution reaction

ORGANIC CHEMISTRY (LL) W/ACCESS, Chapter 22.4, Problem 10CC , additional homework tip  3

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1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the following transformations. b) c) d)

Chapter 22 Solutions

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