ORGANIC CHEMISTRY (LL) W/ACCESS
ORGANIC CHEMISTRY (LL) W/ACCESS
4th Edition
ISBN: 9781119856122
Author: Klein
Publisher: WILEY
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Chapter 22, Problem 50PP
Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed.  The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director.  An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group.  An ammonium group is a meta-director.  An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

ORGANIC CHEMISTRY (LL) W/ACCESS, Chapter 22, Problem 50PP

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Chapter 22 Solutions

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