The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written. Concept introduction: The reagent used in the nitrous acid deamination is the acidified sodium nitrite. The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine . The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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Answer 1

Question

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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Answer 2

Question

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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Check out a sample textbook solution

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Answer 3

Question

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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Answer 4

Question

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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Answer 5

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

Answer 6

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

Answer 7

Chapter 22.15, Problem 17P

Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitroso amine.

The nitrosation of primary amines do not give N-nitroso amine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Prob. 3P Ch. 22.2 - Prob. 4P Ch. 22.4 - Prob. 5P Ch. 22.4 - Prob. 6P Ch. 22.4 - Prob. 7P Ch. 22.4 - Prob. 8P Ch. 22.4 - Prob. 9P Ch. 22.7 - Prob. 10P

Solution Summary: The author explains the mechanism of nitrous acid deamination of 2,2-dimethylpropylamine.

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Chapter 22 Solutions