ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 22.15, Problem 17P
Interpretation Introduction

Interpretation:

The mechanism of nitrous acid deamination of 2,2-dimethylpropylamine is to be written.

Concept introduction:

The reagent used in the nitrous acid deamination is the acidified sodium nitrite.

The nitrosation of secondary amines result in the formation of an isolable intermediate known as N-nitrosoamine.

The nitrosation of primary amines do not give N-nitrosoamine as the intermediate because it is not stable and reacts further to give alkyl diazonium ion.

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