ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 22.1, Problem 3P
Interpretation Introduction

Interpretation:

Thegiven amine have to be classified as primary, secondary, or tertiary amine. An IUPAC name is to be given for the compound.

Concept Introduction:

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The systematic naming of an organic compound is given by IUPAC nomenclature.

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The naming of an organic compound is done such that the structure of organic compound can be correctly interpreted from its name.

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In amines, the nitrogen atom is trivalent and carries an unshared pair of electrons. The nitrogen is sp3 hybridized i.e. it has four sp3 hybrid orbitals.

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In primary amine, two hybridized orbitals overlap with the s orbitals of hydrogen atoms to form two NH sigma bonds.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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