ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
ORGANIC CHEMISTRY (LOOSELEAF)-PACKAGE
10th Edition
ISBN: 9781260008562
Author: Carey
Publisher: MCG
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Chapter 22, Problem 33P
Interpretation Introduction

Interpretation:

Thestructure of quaternary ammonium salt formed by the reaction of physostigmine with methyl iodide is to be predicted.

Concept Introduction:

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The reaction that takes place between an amine and an alkyl halide is a direct nucleophilic substitution reaction.

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The amino group acts as a nucleophile and attacks the electrophilic carbon atom in alkyl halide followed by deprotonation to form amine or ammonium salt.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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