Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
Question
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Chapter 22, Problem 89SCQ

(a)

Interpretation Introduction

Interpretation The dimensions species TiandNi has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions

Ligand field theory: It is used to explain the bonding between metal and ligand in a coordination complex. Ligand field theory is explained in terms of electrostatic interaction of between metal ion and ligands.

Electronic configuration shows the electrons distribution of atoms or molecule in its molecular or atomic orbitals. The electrons are distributed in orbitals by following three important rules, Aufbau's Principle, Pauli-exclusion principle, and Hund's Rule.

If the complex has minimum one unpaired electron, then they are paramagnetic and are attracted towards the magnetic field. If all the electrons are paired in a complex, then they are diamagnetic and are repelled from the magnetic field.

Equation for density is,

  Density=MassVolume

(b)

Interpretation Introduction

Interpretation The density of austenite unit cell has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions

Ligand field theory: It is used to explain the bonding between metal and ligand in a coordination complex. Ligand field theory is explained in terms of electrostatic interaction of between metal ion and ligands.

Electronic configuration shows the electrons distribution of atoms or molecule in its molecular or atomic orbitals. The electrons are distributed in orbitals by following three important rules, Aufbau's Principle, Pauli-exclusion principle, and Hund's Rule.

If the complex has minimum one unpaired electron, then they are paramagnetic and are attracted towards the magnetic field. If all the electrons are paired in a complex, then they are diamagnetic and are repelled from the magnetic field.

Equation for density is,

  Density=MassVolume

(c)

Interpretation Introduction

Interpretation TiandNi atoms are paramagnetic or diamagnetic has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions

Ligand field theory: It is used to explain the bonding between metal and ligand in a coordination complex. Ligand field theory is explained in terms of electrostatic interaction of between metal ion and ligands.

Electronic configuration shows the electrons distribution of atoms or molecule in its molecular or atomic orbitals. The electrons are distributed in orbitals by following three important rules, Aufbau's Principle, Pauli-exclusion principle, and Hund's Rule.

If the complex has minimum one unpaired electron, then they are paramagnetic and are attracted towards the magnetic field. If all the electrons are paired in a complex, then they are diamagnetic and are repelled from the magnetic field.

Equation for density is,

  Density=MassVolume

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Chapter 22 Solutions

Chemistry & Chemical Reactivity

Ch. 22.7 - Prob. 2.2ACPCh. 22.7 - How are the d electrons of Pt distributed in a...Ch. 22.7 - What are the electron configurations for Nd and...Ch. 22.7 - Prob. 3.2ACPCh. 22.7 - Prob. 3.3ACPCh. 22.7 - Prob. 3.4ACPCh. 22 - Identify, based on the position in the periodic...Ch. 22 - Prob. 2PSCh. 22 - Prob. 3PSCh. 22 - Prob. 4PSCh. 22 - Prob. 5PSCh. 22 - Iron is the most abundant transition element in...Ch. 22 - Prob. 7PSCh. 22 - Prob. 8PSCh. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - The lanthanide contraction is given as an...Ch. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Prob. 17PSCh. 22 - Prob. 18PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33PSCh. 22 - Prob. 34PSCh. 22 - Prob. 35PSCh. 22 - Prob. 36PSCh. 22 - Prob. 37PSCh. 22 - Prob. 38PSCh. 22 - Prob. 39PSCh. 22 - Prob. 40PSCh. 22 - Prob. 41PSCh. 22 - Prob. 42PSCh. 22 - Prob. 43PSCh. 22 - Prob. 44PSCh. 22 - Prob. 45PSCh. 22 - Prob. 46PSCh. 22 - Prob. 47PSCh. 22 - Prob. 48PSCh. 22 - Prob. 49PSCh. 22 - Prob. 50PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 52PSCh. 22 - Prob. 53GQCh. 22 - Prob. 54GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 56GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 58GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 61GQCh. 22 - Prob. 62GQCh. 22 - Prob. 63GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 65GQCh. 22 - Prob. 66GQCh. 22 - Prob. 67GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 69GQCh. 22 - Prob. 70GQCh. 22 - Prob. 71GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 77GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 79GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 84GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 89SCQCh. 22 - Prob. 90SCQ
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