Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Textbook Question
Chapter 22, Problem 55QE
Name the following compounds.
- (a) FCH2CH2CH2OH
- (b) CH3CH2CH2NH2
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1. For each of the reaction "railroads" below, you are either asked to give the structure(s) of the starting
material(s) or product(s), or provide reagents/conditions to accomplish the transformation, as
indicated by the boxes.
a.
NaOMe
H+
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HO₂C
MeOH (excess)
MeOH
H3C
Br
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CH3
1. LiAlH4
2. H3O+
3. PBг3
H3C
1. Et-Li
2. H3O+
-CO₂Me
-CO₂Me
OH
CH3
CH3
ল
CH3
Predict the intermediate 1 and final product 2 of this organic reaction:
NaOMe
ག1, ད།་, -
+
H
You can draw 1 and 2 in any arrangement you like.
2
work up
Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge)
bonds at the chiral center.
Explanation
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What is the total energy cost associated with the compound below adopting the shown conformation?
CH3
HH
DH
CH3
Chapter 22 Solutions
Chemistry: Principles and Practice
Ch. 22 - Prob. 1QECh. 22 -
Explain what is special about the element carbon...Ch. 22 - Prob. 3QECh. 22 - Prob. 4QECh. 22 - Prob. 5QECh. 22 - Prob. 6QECh. 22 - Prob. 7QECh. 22 - Prob. 8QECh. 22 - Prob. 9QECh. 22 - Prob. 10QE
Ch. 22 - Prob. 11QECh. 22 - Prob. 12QECh. 22 - Prob. 13QECh. 22 - Prob. 14QECh. 22 - Prob. 15QECh. 22 - Prob. 16QECh. 22 - Prob. 17QECh. 22 - Prob. 18QECh. 22 - Prob. 19QECh. 22 - Prob. 20QECh. 22 - Prob. 21QECh. 22 - Prob. 22QECh. 22 - Prob. 23QECh. 22 - Prob. 24QECh. 22 - Prob. 25QECh. 22 - Prob. 26QECh. 22 - Prob. 27QECh. 22 - Prob. 28QECh. 22 - Prob. 29QECh. 22 - Prob. 30QECh. 22 - Prob. 31QECh. 22 - Prob. 32QECh. 22 - Prob. 33QECh. 22 - Prob. 34QECh. 22 - Prob. 35QECh. 22 - Prob. 36QECh. 22 - Prob. 37QECh. 22 - Prob. 38QECh. 22 - Prob. 39QECh. 22 - Prob. 40QECh. 22 - Prob. 41QECh. 22 - Prob. 42QECh. 22 - Prob. 43QECh. 22 - Prob. 44QECh. 22 - Prob. 45QECh. 22 - Prob. 46QECh. 22 - Prob. 47QECh. 22 - Prob. 48QECh. 22 - Prob. 49QECh. 22 - Prob. 50QECh. 22 - Prob. 51QECh. 22 - Prob. 52QECh. 22 - Prob. 53QECh. 22 - Prob. 54QECh. 22 - Name the following compounds. (a) FCH2CH2CH2OH (b)...Ch. 22 - Prob. 56QECh. 22 - Prob. 57QECh. 22 - Prob. 58QECh. 22 - Prob. 59QECh. 22 - Prob. 60QECh. 22 - Prob. 61QECh. 22 - Prob. 62QECh. 22 - Prob. 63QECh. 22 - Prob. 64QECh. 22 - Prob. 65QECh. 22 - Prob. 66QECh. 22 - Prob. 67QECh. 22 - Prob. 68QECh. 22 - Prob. 69QECh. 22 - Prob. 70QECh. 22 - Prob. 71QECh. 22 - Prob. 72QECh. 22 - Prob. 73QECh. 22 - Prob. 74QECh. 22 - Prob. 75QECh. 22 - Prob. 76QECh. 22 - Prob. 77QECh. 22 - Prob. 78QECh. 22 - Prob. 79QECh. 22 - Prob. 80QECh. 22 - Prob. 81QECh. 22 - Prob. 82QECh. 22 - Prob. 83QECh. 22 - Prob. 84QECh. 22 - Prob. 85QECh. 22 - Prob. 86QECh. 22 - Prob. 87QECh. 22 - Prob. 88QE
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- ΗΝ, Draw Final Product C cyclohexanone pH 4-5 Edit Enamine H3O+ CH3CH2Br THF, reflux H Edit Iminium Ionarrow_forwardHow many hydrogen atoms are connected to the indicated carbon atom?arrow_forwardIdentify the compound with the longest carbon - nitrogen bond. O CH3CH2CH=NH O CH3CH2NH2 CH3CH2C=N CH3CH=NCH 3 The length of all the carbon-nitrogen bonds are the samearrow_forward
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