Name has to be determined for the given compound. Concept Introduction: A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary. IUPAC rules for naming alkanes : There are about five rules that has to be followed for naming an alkane and they are, The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms. Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain. Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering. If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc. Name of the substituents has to be placed in an alphabetical order before the parent compound name.

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Answer 1

Question

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

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Answer 3

Question

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

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Answer 4

Question

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

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Answer 5

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

Answer 6

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

Answer 7

Chapter 22, Problem 27QE

(a)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alkanes:

There are about five rules that has to be followed for naming an alkane and they are,

The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.

Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.

Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.

If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.

Name of the substituents has to be placed in an alphabetical order before the parent compound name.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

IUPAC rules for naming cycloalkanes:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

The number of carbon atoms present in the ring is counted and the name of the alkane that has the same number of carbon atoms is given by adding prefix “cyclo-” to the alkane name.

If the ring is substituted, then the names of the group or atoms have to be placed before the name of cycloalkane. If only one substituent is present, then number is not required.

If the ring contains more than one substituent, then the numbers has to be used in a way that it gives the lowest position for the substituents.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22 - Prob. 1QE Ch. 22 - Explain what is special about the element carbon...Ch. 22 - Prob. 3QE Ch. 22 - Prob. 4QE Ch. 22 - Prob. 5QE Ch. 22 - Prob. 6QE Ch. 22 - Prob. 7QE Ch. 22 - Prob. 8QE Ch. 22 - Prob. 9QE Ch. 22 - Prob. 10QE

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Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

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Chapter 22 Solutions

Concept explainers

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Interpretation: Name has to be determined for the given compound. Concept Introduction: Refer part (a).

Interpretation: Name has to be determined for the given compound. Concept Introduction: Refer part (a).

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Chapter 22 Solutions

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).

Interpretation:

Name has to be determined for the given compound.

Concept Introduction:

Refer part (a).