GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 22, Problem 39E
Interpretation Introduction

(a)

Interpretation:

To show the reaction is likely to go to completion or very nearly so.

Concept introduction:

Reaction which have Keq value greater than 1000 then they are considered to be essentially quantitative. Therefore, below expression is used to calculate Keq.

Ecell0=RTnFlnKeq

Here, R represents gas constant, T represents temperature, n represents number of electron, F represents Faraday’s constant, Keq represents equilibrium constant, and E0cell represents standard electrode potential.

Also,

R=8.314JK1mol1F=94580T=298K

Putting the values,

E cell0=RTnFlnKeqE cell0=8.314JK 1 mol 1×298Kn×96480lnKeq

Or,

Ecell0=0.0257nlnKeq     ....... (1)

Interpretation Introduction

(b)

Interpretation:

To show the reaction is likely to go to completion or very nearly so.

Concept introduction:

Reaction which have Keq value greater than 1000 then they are considered to be essentially quantitative. Therefore, below expression is used to calculate Keq.

Ecell0=RTnFlnKeq

Here, R represents gas constant, T represents temperature, n represents number of electron, F represents Faraday’s constant, Keq represents equilibrium constant, and E0cell represents standard electrode potential.

Also,

R=8.314JK1mol1F=94580T=298K

Putting the values,

E cell0=RTnFlnKeqE cell0=8.314JK 1 mol 1×298Kn×96480lnKeq

Or,

Ecell0=0.0257nlnKeq     ....... (1)

Interpretation Introduction

(c)

Interpretation:

To show the reaction is likely to go to completion or very nearly so.

Concept introduction:

Reaction which have Keq value greater than 1000 then they are considered to be essentially quantitative. Therefore, below expression is used to calculate Keq.

Ecell0=RTnFlnKeq

Here, R represents gas constant, T represents temperature, n represents number of electron, F represents Faraday’s constant, Keq represents equilibrium constant, and E0cell represents standard electrode potential.

Also,

R=8.314JK1mol1F=94580T=298K

Putting the values,

E cell0=RTnFlnKeqE cell0=8.314JK 1 mol 1×298Kn×96480lnKeq

Or,

Ecell0=0.0257nlnKeq     ....... (1)

Interpretation Introduction

(d)

Interpretation:

To show the reaction is likely to go to completion or very nearly so.

Concept introduction:

Reaction which have Keq value greater than 1000 then they are considered to be essentially quantitative. Therefore, below expression is used to calculate Keq.

Ecell0=RTnFlnKeq

Here, R represents gas constant, T represents temperature, n represents number of electron, F represents Faraday’s constant, Keq represents equilibrium constant, and E0cell represents standard electrode potential.

Also,

R=8.314JK1mol1F=94580T=298K

Putting the values,

E cell0=RTnFlnKeqE cell0=8.314JK 1 mol 1×298Kn×96480lnKeq

Or,

Ecell0=0.0257nlnKeq     ....... (1)

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Chapter 22 Solutions

GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

Ch. 22 - Prob. 11ECh. 22 - Prob. 12ECh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Make a general prediction about which of the...Ch. 22 - The following properties of astatine have been...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Each of the following compounds decomposes to...Ch. 22 - Ozone is a power oxidizing agent. Using ozone as...Ch. 22 - Prob. 27ECh. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - In water, O2(aq) is a strong base. If 100.0 mg of...Ch. 22 - The conversion of O2(g) to O2(g) can be...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Joseph Priestley, e British chemist, was credited...Ch. 22 - Give an appropriate name to each of theb following...Ch. 22 - Prob. 44ECh. 22 - Give a specific example of a chemical equation...Ch. 22 - Prob. 46ECh. 22 - Prob. 47ECh. 22 - Prob. 48ECh. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - One reaction that competes with reaction (22.41),...Ch. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Draw plausible Lewis structures for a....Ch. 22 - Both nitramide and hyponitrous acid have the...Ch. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Use data from Table 7.2 (page 273) to calculate...Ch. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - What volume of H2(g) at 25C and 752 mmHg is...Ch. 22 - Prob. 77ECh. 22 - How many grams of CaH2(s) are required to generate...Ch. 22 - Prob. 79ECh. 22 - On the basis of molecular orbital theory, would...Ch. 22 - Prob. 81IAECh. 22 - Prob. 82IAECh. 22 - Prob. 83IAECh. 22 - The photograph was taken after a few drops of a...Ch. 22 - Prob. 85IAECh. 22 - Prob. 86IAECh. 22 - Prob. 87IAECh. 22 - Despite the fact that it has the higher molecular...Ch. 22 - The text mentions that ammonium perchlorate is an...Ch. 22 - Prob. 90IAECh. 22 - Prob. 91IAECh. 22 - Prob. 92IAECh. 22 - Refer to Figure 11-25 to arrange the following...Ch. 22 - Prob. 94IAECh. 22 - Prob. 95IAECh. 22 - Estimate the percent dissociation of CI2(g) into...Ch. 22 - Prob. 97IAECh. 22 - The structure of N(SiH2)2 involves a planar...Ch. 22 - Prob. 99IAECh. 22 - Refer to the Integrative Example on page 1082....Ch. 22 - The bond energies of CIz and 159kJmol1 are 243 and...Ch. 22 - Prob. 102IAECh. 22 - Prob. 103IAECh. 22 - Prob. 104IAECh. 22 - Prob. 105IAECh. 22 - The heavier halogens (CI, Br, and I) form...Ch. 22 - Prob. 107IAECh. 22 - Chemists have successfully synthesized the ionic...Ch. 22 - Prob. 109IAECh. 22 - Various thermochemical cycles are being explored...Ch. 22 - The decomposition of aqueous hydrogen peroxide is...Ch. 22 - Both in this chapter and in Chapter 19, we have...Ch. 22 - Prob. 113FPCh. 22 - The so-called pyroanions, X2O7n+ , form a series...Ch. 22 - A description of bonding in XeF2 based on the...Ch. 22 - Prob. 116FPCh. 22 - Prob. 117SAECh. 22 - Prob. 118SAECh. 22 - Prob. 119SAECh. 22 - Which of the following can oxidize Br to Br2 in...Ch. 22 - Prob. 121SAECh. 22 - Prob. 122SAECh. 22 - Prob. 123SAECh. 22 - Prob. 124SAECh. 22 - Prob. 125SAECh. 22 - Prob. 126SAECh. 22 - Prob. 127SAECh. 22 - Give a practical laboratory method that you might...Ch. 22 - Prob. 129SAECh. 22 - Prob. 130SAECh. 22 - Prob. 131SAECh. 22 - Prob. 132SAECh. 22 - Prob. 133SAECh. 22 - Prob. 134SAECh. 22 - Prob. 135SAE
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