INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
12th Edition
ISBN: 9781337915977
Author: Bettelheim
Publisher: CENGAGE L
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Chapter 22, Problem 22P
4 What kind of
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Draw an appropriate reactant on the left-hand side of this organic reaction.
Also, if any additional major products will be formed, add them to the right-hand side of the reaction.
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1. MCPBA
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drawing a structure.
2. NaOH, H₂O
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Calculate the atomic packing factor of quartz, knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.
3.
a. Use the periodic table to add up the molecular weight of thionyl chloride (SOCl2) and show your work.
b. The actual value obtained for the molecular ion on a high resolution mass spectrometer is 117.9041.
Explain the discrepancy.
c. Show the calculations that correctly result in the exact mass of 117.9041 for SOC₁₂. Use Table 11.2 or
Appendix E in your calculations.
Chapter 22 Solutions
INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
Ch. 22.1 - Prob. 22.1QCCh. 22.2 - Prob. 22.2QCCh. 22.3 - Prob. 22.3QCCh. 22.4 - Which of the following is true regarding enzymes?...Ch. 22.5 - Match the description of the enzyme process with...Ch. 22 - What is the difference between a catalyst and an...Ch. 22 - What are ribozymes made of?Ch. 22 - Would a lipase hydrolyze two triglycerides, one...Ch. 22 - Compare the activation energy in uncatalyzed...Ch. 22 - Prob. 5P
Ch. 22 - Prob. 6PCh. 22 - Prob. 7PCh. 22 - Monoamine oxidases are important enzymes in brain...Ch. 22 - Prob. 9PCh. 22 - 0 What kind of reaction does each of the following...Ch. 22 - Prob. 11PCh. 22 - In most enzyme-catalyzed reactions, the rate of...Ch. 22 - 5 At a very low concentration of a certain...Ch. 22 - 6 If we wish to double the rate of an...Ch. 22 - 7 A bacterial enzyme has the following...Ch. 22 - 8 The optimal temperature for the action of...Ch. 22 - 9 The activity of pepsin was measured at various...Ch. 22 - Prob. 18PCh. 22 - Prob. 19PCh. 22 - Prob. 20PCh. 22 - Prob. 21PCh. 22 - 4 What kind of chemical reaction occurs most...Ch. 22 - 5 Which of the following is a correct statement...Ch. 22 - Prob. 24PCh. 22 - 7 Enzymes are long protein chains, usually...Ch. 22 - Prob. 26PCh. 22 - Prob. 27PCh. 22 - 0 Can the product of a reaction that is part of a...Ch. 22 - 1 What is the difference between a zymogen and a...Ch. 22 - 2 The enzyme trypsin is synthesized by the body in...Ch. 22 - Prob. 31PCh. 22 - Prob. 32PCh. 22 - Prob. 33PCh. 22 - Prob. 34PCh. 22 - Prob. 35PCh. 22 - Prob. 36PCh. 22 - Prob. 37PCh. 22 - Prob. 38PCh. 22 - 1 After a heart attack, the levels of certain...Ch. 22 - Prob. 40PCh. 22 - Prob. 41PCh. 22 - Prob. 42PCh. 22 - 5 Chemists who have been exposed for years to or...Ch. 22 - 6 Which enzyme preparation is given to patients...Ch. 22 - 7 Chymotrypsm is secreted by the pancreas and...Ch. 22 - Prob. 46PCh. 22 - Prob. 47PCh. 22 - Prob. 48PCh. 22 - Prob. 49PCh. 22 - Prob. 50PCh. 22 - Prob. 51PCh. 22 - Prob. 52PCh. 22 - Prob. 53PCh. 22 - Prob. 54PCh. 22 - Prob. 55PCh. 22 - Prob. 56PCh. 22 - Prob. 57PCh. 22 - Prob. 58PCh. 22 - Prob. 59PCh. 22 - Prob. 60PCh. 22 - 1 Food can be preserved by inactivation of enzymes...Ch. 22 - Prob. 62PCh. 22 - 3 Would you expect to find active digestive...Ch. 22 - Prob. 64PCh. 22 - Prob. 65PCh. 22 - Prob. 66PCh. 22 - 7 An enzyme has the following pH dependence: At...Ch. 22 - Prob. 68PCh. 22 - Prob. 69PCh. 22 - 0 Nerve gases operate by forming covalent bonds at...Ch. 22 - 1 What would be the appropriate name for an enzyme...Ch. 22 - Prob. 72PCh. 22 - 3 A liver enzyme is made of four subunits: 2A and...Ch. 22 - Prob. 74PCh. 22 - Prob. 75PCh. 22 - Prob. 76PCh. 22 - Prob. 77PCh. 22 - Prob. 78PCh. 22 - Prob. 79PCh. 22 - Prob. 80PCh. 22 - Prob. 81P
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- 6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B₂2+ B22+, B2, C22, B22- and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?arrow_forwardDon't used hand raitingarrow_forwardEXERCISES: Complete the following exercises. You must show all work to receive full credit. 1. How many molecular orbitals can be built from the valence shell orbitals in O2? 2. Give the ground state electron configuration (e.g., 02s² 0*2s² П 2p²) for these molecules and deduce its bond order. Ground State Configuration Bond Order H2+ 02 N2arrow_forward
- 7. Draw the Lewis structures and molecular orbital diagrams for CO and NO. What are their bond orders? Are the molecular orbital diagrams similar to their Lewis structures? Explain. CO Lewis Structure NO Lewis Structure CO Bond Order NO Bond Order CO Molecular Orbital Diagram NO Molecular Orbital Diagramarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardDraw the condensed structure of 4-ethyl-1,2,4-trifluoro-2-methyloctane.arrow_forward
- 5. The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Label the molecular orbital diagram for XeF (include atom chemical symbol, atomic orbitals, and molecular orbitals) and deduce its ground state electron configuration. Is XeF likely to have a shorter bond length than XeF+? XeF XeF+ Bond Orderarrow_forwardDon't used hand raitingarrow_forward4. The superoxide ion, Oz, plays an important role in the ageing processes that take place in organisms. Judge whether O2 is likely to have larger or smaller dissociation energy than O2. Molecular Orbital Diagram 8 02 02 Does O2 have larger or smaller dissociation energy?: Bond Orderarrow_forward
- Will a weak base with a pKa of 8.4 be best absorbed in the stomach or the intestine? Explain your reasoning behind your answer. Use a chemical equilibrium equation in your answer.arrow_forwardYou have started a patient on a new drug. Each dose introduces 40 pg/mL of drug after redistribution and prior to elimination. This drug is administered at 24 h intervals and has a half life of 24 h. What will the concentration of drug be after each of the first six doses? Show your work a. What is the concentration after the first dose? in pg/mL b. What is the concentration after the second dose? in pg/mL c. What is the concentration after the third dose? in pg/mLarrow_forwardHow many different molecules are drawn below?arrow_forward
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