Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Chapter 22, Problem 22.64E
Interpretation Introduction
Interpretation:
The food in breakfast meal that can acts as the source of lysine is to be stated.
Concept introduction:
Amino acids are organic compounds which combine sequentially to generate a protein. They are known as the building blocks of the human body. The essential amino acids are valine, lysine, histidine, methionine, threonine, isoleucine, tryptophan, phenylalanine and leucine
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 22 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 22 - Prob. 22.1ECh. 22 - Prob. 22.2ECh. 22 - Prob. 22.3ECh. 22 - List two general functions in the body for each of...Ch. 22 - Prob. 22.5ECh. 22 - Prob. 22.6ECh. 22 - Prob. 22.7ECh. 22 - Prob. 22.8ECh. 22 - Prob. 22.9ECh. 22 - Identify each of the following vitamins as...
Ch. 22 - Prob. 22.11ECh. 22 - Prob. 22.12ECh. 22 - Prob. 22.13ECh. 22 - Prob. 22.14ECh. 22 - Prob. 22.15ECh. 22 - Prob. 22.16ECh. 22 - Prob. 22.17ECh. 22 - What are the general functions of trace minerals...Ch. 22 - Prob. 22.19ECh. 22 - Prob. 22.20ECh. 22 - Prob. 22.21ECh. 22 - Prob. 22.22ECh. 22 - Prob. 22.23ECh. 22 - Prob. 22.24ECh. 22 - What is a metabolic pathway?Ch. 22 - Prob. 22.26ECh. 22 - Prob. 22.27ECh. 22 - Prob. 22.28ECh. 22 - Prob. 22.29ECh. 22 - Prob. 22.30ECh. 22 - Prob. 22.31ECh. 22 - Prob. 22.32ECh. 22 - Prob. 22.33ECh. 22 - Prob. 22.34ECh. 22 - Prob. 22.35ECh. 22 - Prob. 22.36ECh. 22 - Using symbolic formulas such as ADP and PPi, write...Ch. 22 - Prob. 22.38ECh. 22 - Prob. 22.39ECh. 22 - Prob. 22.40ECh. 22 - Prob. 22.41ECh. 22 - Prob. 22.42ECh. 22 - Prob. 22.43ECh. 22 - Prob. 22.44ECh. 22 - Prob. 22.45ECh. 22 - Prob. 22.46ECh. 22 - Prob. 22.47ECh. 22 - Prob. 22.48ECh. 22 - Prob. 22.49ECh. 22 - Prob. 22.50ECh. 22 - Prob. 22.51ECh. 22 - Prob. 22.52ECh. 22 - Prob. 22.53ECh. 22 - Prob. 22.54ECh. 22 - Prob. 22.55ECh. 22 - Prob. 22.56ECh. 22 - Prob. 22.57ECh. 22 - Prob. 22.58ECh. 22 - Prob. 22.59ECh. 22 - Prob. 22.60ECh. 22 - Prob. 22.61ECh. 22 - Prob. 22.62ECh. 22 - Prob. 22.63ECh. 22 - Prob. 22.64ECh. 22 - Prob. 22.65ECh. 22 - Prob. 22.66ECh. 22 - Prob. 22.67ECh. 22 - Prob. 22.68ECh. 22 - Which of the following are not a requirement for...Ch. 22 - Prob. 22.70ECh. 22 - Prob. 22.71ECh. 22 - Outline the three stages in the extraction of...Ch. 22 - Prob. 22.73ECh. 22 - Prob. 22.74ECh. 22 - Prob. 22.75ECh. 22 - Prob. 22.76ECh. 22 - Prob. 22.77E
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