(a) Interpretation: An explanation as to why bromobenzene is inert is to be stated. Concept introduction: The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The S N 2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

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Answer 1

Question

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

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The decomposition of dinitrogen pentoxide according to the equation: 50°C 2 N2O5(g) 4 NO2(g) + O2(g) follows first-order kinetics with a rate constant of 0.0065 s-1. If the initial concentration of N2O5 is 0.275 M, determine: the final concentration of N2O5 after 180 seconds. ...

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CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?

Answer 2

Question

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

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Answer 3

Question

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

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Answer 4

Question

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

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Answer 5

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Answer 6

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Answer 7

Chapter 22, Problem 22.37P

Interpretation Introduction

(a)

Interpretation:

An explanation as to why bromobenzene is inert is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The role of the catalyst in the given mechanism is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks at the electrophilic centre. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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Chapter 22 Solutions