(a) Interpretation: The product formed on Aldol condensation in the given reaction is to be stated. Concept introduction: In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 1

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Answer 2

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 3

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 4

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 5

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 6

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 7

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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