(a) Interpretation: The conjugate base structure of the given compound and relation between them is to be stated. Concept introduction: Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

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Answer 1

Question

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

Answer 2

Question

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

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Answer 3

Question

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

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Answer 4

Question

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

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Answer 5

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Answer 6

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Answer 7

Chapter 22, Problem 22.61AP

Interpretation Introduction

(a)

Interpretation:

The conjugate base structure of the given compound and relation between them is to be stated.

Concept introduction:

Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Among the given compounds, the more acidic compound with an energy diagram is to be stated.

Concept introduction:

Brønsted bases are those species which accept a proton. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. Acid loses a proton and forms conjugate base. The acidity of the compound depends upon the stability of its conjugate base. The more stable the conjugate base, the more acidic is the compound. It also depends on the charge, inductive effects, the role of atom present.

Answer 10

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that Brnsted acids are those species which donate a proton.

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Chapter 22 Solutions