General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 22, Problem 22.32SP
Interpretation Introduction
Interpretation:
The particle used for the bombardment in the given nuclear reaction has to be predicted.
Concept Introduction:
Balancing nuclear reaction equation: The balanced nuclear reaction should conserve both mass number and atomic number.
- The sum of the mass numbers of the reactants should be equal to the sum of mass numbers of the products in the reaction.
- The sum of
atomic numbers (or the atomic charge) of the reactants should be equal to the sum of atomic numbers (or the atomic charge) of the products in the reaction.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 22 Solutions
General Chemistry: Atoms First
Ch. 22.1 - Prob. 22.1PCh. 22.2 - Prob. 22.2PCh. 22.2 - Prob. 22.3PCh. 22.3 - Prob. 22.4PCh. 22.3 - Prob. 22.5PCh. 22.4 - Prob. 22.6PCh. 22.4 - Prob. 22.7PCh. 22.6 - Prob. 22.8PCh. 22.6 - Prob. 22.9PCh. 22 - Prob. 22.10SP
Ch. 22 - Prob. 22.11SPCh. 22 - Prob. 22.12SPCh. 22 - Prob. 22.13SPCh. 22 - Prob. 22.14SPCh. 22 - Prob. 22.15SPCh. 22 - Prob. 22.16SPCh. 22 - Prob. 22.17SPCh. 22 - Prob. 22.18SPCh. 22 - Prob. 22.19SPCh. 22 - Prob. 22.20SPCh. 22 - Prob. 22.21SPCh. 22 - Prob. 22.22SPCh. 22 - Prob. 22.23SPCh. 22 - Prob. 22.24SPCh. 22 - Prob. 22.25SPCh. 22 - Prob. 22.26SPCh. 22 - Prob. 22.27SPCh. 22 - Prob. 22.28SPCh. 22 - Prob. 22.29SPCh. 22 - Prob. 22.30SPCh. 22 - Prob. 22.31SPCh. 22 - Prob. 22.32SPCh. 22 - Prob. 22.33SPCh. 22 - Prob. 22.36CHPCh. 22 - Prob. 22.37CHPCh. 22 - Prob. 22.38CHPCh. 22 - Prob. 22.39CHPCh. 22 - Prob. 22.40CHPCh. 22 - Prob. 22.41CHPCh. 22 - Prob. 22.42CHPCh. 22 - Prob. 22.43CHPCh. 22 - Prob. 22.44CHPCh. 22 - Prob. 22.45CHPCh. 22 - Prob. 22.46CHPCh. 22 - Prob. 22.47CHPCh. 22 - Prob. 22.48MPCh. 22 - Prob. 22.49MPCh. 22 - Prob. 22.50MPCh. 22 - Prob. 22.51MP
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