General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 22, Problem 22.44CHP
Interpretation Introduction

Interpretation:

The Gamma-radiation energy released in kJ/mol in the given nuclear reaction has to be calculated.

Concept Introduction:

Nuclear reaction: A nuclear reaction in which a lighter nucleus fuse together spontaneously into new stable nuclei or heavier nuclei split into daughter nuclei with the release of large amount of energy.

Energy released in nuclear reaction: The mass change of the reaction is calculated; and using Einstein mass-energy relation, ΔE = Δmc2

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Given the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism:  1) NO + NO ⇄ N2O2 (fast);   2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
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