If the given proposed reaction takes place quickly under mild conditions or not is to be identified. Concept introduction: The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

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Answer 1

Question

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

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Dr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v V

Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

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Answer 3

Question

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

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Answer 4

Question

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

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Answer 5

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 6

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 7

Chapter 21.5C, Problem 21.7P

(a)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of the leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 8

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 9

(b)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophilic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 10

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 11

(c)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 12

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 13

(d)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 14

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 15

(e)

Interpretation Introduction

Interpretation:

If the given proposed reaction takes place quickly under mild conditions or not is to be identified.

Concept introduction:

The chemical reaction in which species with negative charge or lone pair of electrons attack on electron deficient atom and occupy the position of leaving group is called nucleophillic substitution reaction. In case of nucleophilic substitution, an electron rich species attacks the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of the leaving group from the substrate.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author explains the nucleophilic substitution reaction, where an electron rich species attacks the species that is deficient in electrons.

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Chapter 21 Solutions