The order of given compounds in increasing rate of nucleophilic attack at C = O by a strong nucleophile is to be predicted. Concept introduction: The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

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Answer 1

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1

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Answer 2

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 3

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 4

Question

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

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Answer 5

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 6

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

Answer 7

Chapter 21, Problem 21.59SP

(a)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will be its stability.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The order of given compounds in increasing rate of nucleophilic attack at C=O by a strong nucleophile is to be predicted.

Concept introduction:

The rate of nucleophilic attack on compound is determined by the stability of the compound. More is the stability of a compound; less is the rate of the reaction. The stability of compound depends upon the number of resonating structures. More the resonating structures of compound more will its stability.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author explains that the rate of nucleophilic attack on compound is determined by the stability of the compound.

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