The structure of the disulfide formed when cysteine is oxidized needs to be determined. Concept introduction: The functional group R − S − S − R ' refers disulfide. This bond is called disulfide bridge or S − S bond. The S − S bond is derived from the coupling of two thiol group.

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Answer 1

Question

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

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81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

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Answer 2

Question

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

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Answer 3

Question

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Expert Solution & Answer

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Answer 4

Question

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Expert Solution & Answer

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Answer 5

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Answer 6

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Answer 7

Chapter 21.5, Problem 21.12P

Interpretation Introduction

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 21.2 - In addition to the amino and carboxyl groups, what...Ch. 21.2 - Draw both enantiomers of each amino acid in...Ch. 21.2 - Prob. 21.3P Ch. 21.3 - Draw the structure of the amino acid valine at...Ch. 21.3 - Identify the amino acid shown with all uncharged...Ch. 21.4 - Identify the N-terminal and C-terminal amino acid...Ch. 21.4 - Prob. 21.7P Ch. 21.4 - Prob. 21.8P Ch. 21.4 - Prob. 21.9P Ch. 21.4 - Prob. 21.10P

The structure of the disulfide formed when cysteine is oxidized needs to be determined. Concept introduction: The functional group R − S − S − R ' refers disulfide. This bond is called disulfide bridge or S − S bond. The S − S bond is derived from the coupling of two thiol group.

Solution Summary: The author explains that the structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept explainers

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Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Want to see the full answer?

Chapter 21 Solutions

The structure of the disulfide formed when cysteine is oxidized needs to be determined. Concept introduction: The functional group R − S − S − R ' refers disulfide. This bond is called disulfide bridge or S − S bond. The S − S bond is derived from the coupling of two thiol group.

Solution Summary: The author explains that the structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept explainers

Videos

Interpretation: The structure of the disulfide formed when cysteine is oxidized needs to be determined. Concept introduction: The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The structure of the disulfide formed when cysteine is oxidized needs to be determined.

Concept introduction:

The functional group R−S−S−R' refers disulfide. This bond is called disulfide bridge or S−S bond. The S−S bond is derived from the coupling of two thiol group.