EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 21, Problem 21.46P
Interpretation Introduction
Interpretation:
The N-terminal and C-terminal amino acids in a given ball-and-stick model should be labeled. The name of the dipeptide should be predicted using a one-letter abbreviation for the amino acids.
Concept Introduction:
The organic compound that is composed of an amino group and carboxylic group along with an organic chain is known as an amino acid.
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
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G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 21 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 21.2 - In addition to the amino and carboxyl groups, what...Ch. 21.2 - Draw both enantiomers of each amino acid in...Ch. 21.2 - Prob. 21.3PCh. 21.3 - Draw the structure of the amino acid valine at...Ch. 21.3 - Identify the amino acid shown with all uncharged...Ch. 21.4 - Identify the N-terminal and C-terminal amino acid...Ch. 21.4 - Prob. 21.7PCh. 21.4 - Prob. 21.8PCh. 21.4 - Prob. 21.9PCh. 21.4 - Prob. 21.10P
Ch. 21.4 - Prob. 21.11PCh. 21.5 - Prob. 21.12PCh. 21.6 - Prob. 21.13PCh. 21.6 - Prob. 21.14PCh. 21.6 - Prob. 21.15PCh. 21.7 - Why is hemoglobin more water soluble than ...Ch. 21.8 - Prob. 21.17PCh. 21.8 - Prob. 21.18PCh. 21.9 - Prob. 21.19PCh. 21.9 - Prob. 21.20PCh. 21.9 - Prob. 21.21PCh. 21.9 - Prob. 21.22PCh. 21.10 - Prob. 21.23PCh. 21.10 - Prob. 21.24PCh. 21.10 - Prob. 21.25PCh. 21.10 - Prob. 21.26PCh. 21.10 - Prob. 21.27PCh. 21.10 - Prob. 21.28PCh. 21.10 - Prob. 21.29PCh. 21.11 - Prob. 21.30PCh. 21 - The amino acid alanine is a solid at room...Ch. 21 - Why is phenylalanine water soluble but...Ch. 21 - Draw the structure of a naturally occurring amino...Ch. 21 - Draw the structure of a naturally occurring amino...Ch. 21 - For each amino acid: [1] draw the L enantiomer in...Ch. 21 - For each amino acid: [1] draw the L enantiomer in...Ch. 21 - Draw both enantiomers of each amino acid and label...Ch. 21 - Which of the following Fischer projections...Ch. 21 - For each amino acid: [1] give the name; [2] give...Ch. 21 - For each amino acid: [1] give the name; [2] give...Ch. 21 - (a) Identify the amino acid shown with all...Ch. 21 - Prob. 21.42PCh. 21 - Prob. 21.43PCh. 21 - Draw the structure of the neutral, positively...Ch. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - (a) Draw the structure of the two possible...Ch. 21 - Prob. 21.48PCh. 21 - Prob. 21.49PCh. 21 - For each tripeptide: [1] draw the structure of the...Ch. 21 - Prob. 21.51PCh. 21 - For each tripeptide: [1] identify the amino acids...Ch. 21 - Prob. 21.53PCh. 21 - Prob. 21.54PCh. 21 - Prob. 21.55PCh. 21 - Prob. 21.56PCh. 21 - Prob. 21.57PCh. 21 - Prob. 21.58PCh. 21 - Prob. 21.59PCh. 21 - Prob. 21.60PCh. 21 - Prob. 21.61PCh. 21 - Prob. 21.62PCh. 21 - What type of intermolecular forces exist between...Ch. 21 - What type of interaction occur at each of the...Ch. 21 - Prob. 21.65PCh. 21 - Draw the structures of the amino acids tyrosine...Ch. 21 - Prob. 21.67PCh. 21 - Prob. 21.68PCh. 21 - Prob. 21.69PCh. 21 - Prob. 21.70PCh. 21 - Prob. 21.71PCh. 21 - Hydrogen bonding stabilizes both the secondary and...Ch. 21 - Prob. 21.73PCh. 21 - Prob. 21.74PCh. 21 - Prob. 21.75PCh. 21 - Prob. 21.76PCh. 21 - What class of enzyme catalyzes each of the...Ch. 21 - What class of enzyme catalyzes each of the...Ch. 21 - Prob. 21.79PCh. 21 - Prob. 21.80PCh. 21 - Prob. 21.81PCh. 21 - What kind of reaction is catalyzed by each of the...Ch. 21 - Prob. 21.83PCh. 21 - How will each of the following changes affect the...Ch. 21 - Prob. 21.85PCh. 21 - Prob. 21.86PCh. 21 - Prob. 21.87PCh. 21 - Prob. 21.88PCh. 21 - Prob. 21.89PCh. 21 - Prob. 21.90PCh. 21 - Prob. 21.91PCh. 21 - Prob. 21.92PCh. 21 - Why must vegetarian diets be carefully balanced?Ch. 21 - Prob. 21.94PCh. 21 - Sometimes an incision is cauterized (burned) to...Ch. 21 - Why is insulin administered by injection instead...Ch. 21 - Prob. 21.97PCh. 21 - The silk produced by a silkworm is a protein with...Ch. 21 - Explain the difference in the mechanism of action...Ch. 21 - Prob. 21.100PCh. 21 - Prob. 21.101CPCh. 21 - Suggest a reason for the following observation....
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