EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
7th Edition
ISBN: 9781119360889
Author: HYSLOP
Publisher: VST
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 21, Problem 86RQ
Sketch the d-orbital energy level diagrams for
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
The orbital occupancies for the d orbitals of several com-plex ions are diagrammed below. (a) Which diagram corresponds to the orbital occupancy of thecobalt ion in [Co(CN)₆]³⁻? (b) If diagram D depicts the orbital occupancy of the cobalt ionin [CoF₆]ⁿ, what is the value of n? (c) [NiCl₄]²⁻ is paramagnetic and [Ni(CN)₄]²⁻ is diamagnetic.Which diagrams correspond to the orbital occupancies of thenickel ions in these species? (d) Diagram C shows the orbital occupancy of V²⁺ in the octa-hedral complex VL₆. Can you determine whether L is a strong-or weak-field ligand? Explain.
Draw the octahedral crystal field d orbital splitting diagrams for [Fe(OH2)6] 2+ and [Fe(CN)6] 3. Indicate if the
diagrams are high spin and low spin. give the names of the d-orbitals (dxz, dxy, dzy, dz2, dx2 - y2) label the appropriate
orbital sets eg* and t2g and show how the electrons populate the diagram. (Hint: Pairing energy for 3d orbitals Fe
2+ = 29875 cm-1, Fe 3+ = 19150 cm-1; delta OH for Fe(OH2)6]2+ = 14300 cm-1 and delta OH for [Fe(CN)6]3 - is
35000 cm-1
The self exchange electron-transfer reaction between [Co(en)3]3+ and [Co(en)3]2+ is rather slow. Explain this observation on the basis of d-orbital occupations.
Chapter 21 Solutions
EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
Ch. 21 - Prob. 1PECh. 21 - Aluminum chloride crystallizes from aqueous...Ch. 21 - What is the formula of the complex ion that is...Ch. 21 - Prob. 4PECh. 21 - Prob. 5PECh. 21 - Prob. 6PECh. 21 - What is the coordination number of the metal ion...Ch. 21 - What is the coordination number of the metal ion...Ch. 21 - Prob. 9PECh. 21 - Prob. 10PE
Ch. 21 - Prob. 11PECh. 21 - Prob. 12PECh. 21 - The iron metal center in hemoglobin sits in an...Ch. 21 - Prob. 1RQCh. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Complex Ions Use Lewis structures to diagram the...Ch. 21 - Complex Ions
21.6 What must be true about the...Ch. 21 - Prob. 7RQCh. 21 - Complex Ions What is a chelate? Use Lewis...Ch. 21 - Prob. 9RQCh. 21 - Complex Ions Explain how a sale of EDTA4- can...Ch. 21 - Prob. 11RQCh. 21 - Complex Ions
21.12 The cobalt(III) ion, , forms a...Ch. 21 - Prob. 13RQCh. 21 - Complex Ions What is the chelate effect? How does...Ch. 21 - Prob. 15RQCh. 21 - Prob. 16RQCh. 21 - Prob. 17RQCh. 21 - Prob. 18RQCh. 21 - Prob. 19RQCh. 21 - Prob. 20RQCh. 21 - Prob. 21RQCh. 21 - Prob. 22RQCh. 21 - Prob. 23RQCh. 21 - Prob. 24RQCh. 21 - Coordination Number and Structure Draw (a) a...Ch. 21 - Prob. 26RQCh. 21 - Prob. 27RQCh. 21 - Prob. 28RQCh. 21 - Prob. 29RQCh. 21 - Prob. 30RQCh. 21 - Prob. 31RQCh. 21 - Bonding in Metal Complexes
21.32 On appropriate...Ch. 21 - Prob. 33RQCh. 21 - Prob. 34RQCh. 21 - Prob. 35RQCh. 21 - Prob. 36RQCh. 21 - Prob. 37RQCh. 21 - Prob. 38RQCh. 21 - Prob. 39RQCh. 21 - Prob. 40RQCh. 21 - Prob. 41RQCh. 21 - Prob. 42RQCh. 21 - Bonding in Metal Complexes What factors about the...Ch. 21 - Prob. 44RQCh. 21 - Bonding in Metal Complexes The complex [...Ch. 21 - Bonding in Metal Complexes
21.46 Consider the...Ch. 21 - Prob. 47RQCh. 21 - Prob. 48RQCh. 21 - Prob. 49RQCh. 21 - Prob. 50RQCh. 21 - Prob. 51RQCh. 21 - Biological Functions of Metals Ions
21.52 List...Ch. 21 - Prob. 53RQCh. 21 - Prob. 54RQCh. 21 - Prob. 55RQCh. 21 - Write the formula, including its correct charge,...Ch. 21 - Metal Complex Nomenclature How would the following...Ch. 21 - Metal Complex Nomenclature
21.58 How would the...Ch. 21 - Give IUPAC names for each of the following:...Ch. 21 - Prob. 60RQCh. 21 - Prob. 61RQCh. 21 - Prob. 62RQCh. 21 - Coordination Number and Structure
21.63 What is...Ch. 21 - Prob. 64RQCh. 21 - Draw a reasonable structure for (a) [ Zn(NH3)4 ]2+...Ch. 21 - Prob. 66RQCh. 21 - Prob. 67RQCh. 21 - 21.68 The following compound is called...Ch. 21 - Prob. 69RQCh. 21 - Isomers of Metal Complexes
*21.70 Below is a...Ch. 21 - Prob. 71RQCh. 21 - Prob. 72RQCh. 21 - Prob. 73RQCh. 21 - Prob. 74RQCh. 21 - Bonding in Metal Complexes
*21.75 In which complex...Ch. 21 - Prob. 76RQCh. 21 - Prob. 77RQCh. 21 - Prob. 78RQCh. 21 - Prob. 79RQCh. 21 - Prob. 80RQCh. 21 - Referring to the two ligands, A and B, described...Ch. 21 - Referring to the complexes in Problems 21.80 and...Ch. 21 - Prob. 83RQCh. 21 - Prob. 84RQCh. 21 - *21.85 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.86 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.87 ions can be either four coordinate or six...Ch. 21 - Prob. 88RQCh. 21 - Most of the first row transition metals form 2+...Ch. 21 - *21.90 Is the complex chiral? Illustrate your...Ch. 21 - The complex [PtCl2(NH3)2] can be obtained as two...Ch. 21 - Prob. 92RQCh. 21 - Prob. 93RQCh. 21 - The compound Cr2(NH3)3(H2O)3Cl is a neutral salt...Ch. 21 - Prob. 95RQCh. 21 - Prob. 96RQCh. 21 - Prob. 97RQCh. 21 - Prob. 98RQCh. 21 - Prob. 99RQCh. 21 - Platinum(IV) makes compounds with coordination...Ch. 21 - Prob. 101RQCh. 21 - Prob. 102RQ
Additional Science Textbook Solutions
Find more solutions based on key concepts
2. Define equilibrium population. Outline the conditions that must be met for a population to stay in genetic e...
Biology: Life on Earth (11th Edition)
4. The lipid portion of a typical bilayers is about 30 A0 thick.
a. Calculate the minimum number of residues in...
Biochemistry: Concepts and Connections (2nd Edition)
What are the functions of the hyoid bone?
Principles of Anatomy and Physiology
33. Write an equilibrium expression for each chemical equation for each chemical equation involving one or more...
Chemistry: Structure and Properties (2nd Edition)
56. Global Positioning System. Learn more about the global positioning system and its uses. Write a short repo...
The Cosmic Perspective (8th Edition)
All of the following terms can appropriately describe humans except: a. primary consumer b. autotroph c. hetero...
Human Biology: Concepts and Current Issues (8th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Identify, based on the position in the periodic table, the actinide elements among those in the following list: Co, Cm, Cd, Ce, Cf.arrow_forwardhas a crystal field splitting energy, o, of 2.60102 kJ/mol. What is the wavelength responsible for this energy?arrow_forwardThe ferrate ion, FeO42, is such a powerful oxidizing agent that in acidic solution, aqueous ammonia is reduced to elemental nitrogen along with the formation of the iron(III) ion. a. What is the oxidation state of iron in FeO42, and what is the electron configuration of iron in this polyatornic ion? b. lf 25.0 mL of a 0.243 M FeO42 solution is allowed to react with 55.0 mL of 1.45 M aqueous ammonia, what volume of nitrogen gas can form at 25C and 1.50 atm?arrow_forward
- Give the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+ (b) Mn3+ (c) Ag+ (d) Pt4+ (e) Au3+arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forward
- There are only two geometric isomers of the tetraamminedichlorocobalt(III) ion, [Co(NH3)4Cl2]+. How many geometric isomers would be expected for this ion if it had a regular planar hexagonal geometry? Give drawings for them. Does this rule out a planar hexagonal geometry for [Co(NH3)4Cl2]+? Explain.arrow_forwardPlease predict the number of unpaired electrons in [Ni(CN)4]² and [Fe(CN)6]*, explain your results using crystal field theory.arrow_forwardWhich is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+arrow_forward
- Use the thermodynamic data given below to compute the formation constant, Kf for [Zn(NH3)4]2+ in aqueous solution at 337.0 K. Species ΔfH0kJ/mol S0J/mol/K NH3(aq) -80.29 111.3 Zn2+(aq) -153.89 -112.1 [Zn(NH3)4]2+(aq) -533.5 301 Include 3 significant figuresarrow_forwardHow many unpaired electrons do you predict for the tetrahedral [MnCl4]2- ion?arrow_forwardExplain why the [Fe(CN)6]3- ion has one unpaired electron, while the [Fe(NCS)6]3- ion has five unpaired electrons. Clearly explain the reason for your answer.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Lanthanoids and its Position in Periodic Table - D and F Block Elements - Chemistry Class 12; Author: Ekeeda;https://www.youtube.com/watch?v=ZM04kRxm6tY;License: Standard YouTube License, CC-BY