The formulas for the given coordination compounds are to be stated. Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically. To determine: The formula of given coordination compound.

Question

What are the major products of the following enolate alkylation reaction? Please include a detailed explanation as well as a drawing as to how the reaction proceeds.

Answer 1

Question

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

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What are the major products of the following enolate alkylation reaction? Please include a detailed explanation as well as a drawing as to how the reaction proceeds.

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Potential Energy (kJ) 1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. AH = -950 kJ AH = 575 kJ (i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s) Ea = 1550 kJ (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2240 kJ Ea = 2350 kJ AH = -825 kJ 2600 2400 2200 2000 1800 1600 1400 1200 1000 a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ 800 600 400 200 0 -200- -400 -600- -800- Reaction Progress

Answer 2

Question

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

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Answer 3

Question

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

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Answer 4

Question

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

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Answer 5

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 6

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 7

Chapter 21, Problem 79AE

(a)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 8

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

Answer 9

(b)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

The formula of given coordination compound is [Cr(NH3)5I]I2 .

Answer 10

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 11

(c)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 12

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 13

(d)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 14

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 15

(e)

Interpretation Introduction

Interpretation: The formulas for the given coordination compounds are to be stated.

Concept introduction: Rules should be followed to give formula to any coordination compound. Cations are named before anions and the ligands are named before the metal ion. Prefixes are used to denote the number of ligands. Oxidation state of central metal ion is designated by a roman numeral in parentheses. Ligands are named alphabetically.

To determine: The formula of given coordination compound.

Answer 16

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Answer 27

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains the formulas for hexakis (pyridine)cobalt(III) chloride.

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Chapter 21 Solutions