The correct crystal field diagram for the given complex is to be identified. Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin. To determine: If the given crystal field diagram for Zn ( NH 3 ) 4 2+ is correct or not. The given crystal field diagram for Zn ( NH 3 ) 4 2+ is not correct.

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Answer 1

Question

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

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Answer 2

Question

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Answer 6

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

Answer 7

Chapter 21, Problem 87CWP

(a)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Zn(NH3)42+ is correct or not.

The given crystal field diagram for Zn(NH3)42+ is not correct.

Answer 8

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

Answer 9

(b)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Mn(CN)63+ is correct or not.

Answer 10

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Answer 11

(c)

Interpretation Introduction

Interpretation: The correct crystal field diagram for the given complex is to be identified.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: If the given crystal field diagram for Ni(CN)42- is correct or not.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached.

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Chapter 21 Solutions