The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated. Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin. To determine: The optically active isomers of the given compound.

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Answer 1

Question

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

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Answer 2

Question

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

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Answer 3

Question

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

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Answer 4

Question

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

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Answer 5

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

Answer 6

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

Answer 7

Chapter 21, Problem 74AE

(a)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The optically active isomers of the given compound.

Answer 8

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

Answer 9

(b)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The oxidation states of cobalt ions in the compound.

Answer 10

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

Answer 11

(c)

Interpretation Introduction

Interpretation: The optically active isomers of the given compound are to be drawn. Oxidation state of the cobalt ions and the number of unpaired electrons present if the complex is the low spin are to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that the optically active isomers of the given compound are to be drawn. Oxidation state of cobalt ions and the number of unpaired electrons present if the complex is the low spin

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Chapter 21 Solutions