Concept explainers
(a)
Interpretation: The two isomers of
Concept introduction: Organic compounds which have similar chemical formula but different structures, i.e., the atoms are in a different spatial arrangement, they are known as structural isomers. Cis and Trans isomers are also structural or geometrical isomers. Optical isomers are those which have non super imposable mirror images.
To determine: The two isomers of
(b)
Interpretation: The two isomers of
Concept introduction: Organic compounds which have similar chemical formula but different structures, i.e., the atoms are in a different spatial arrangement, they are known as structural isomers. Cis and Trans isomers are also structural or geometrical isomers. Optical isomers are those which have non super imposable mirror images.
To determine: The two isomers of
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Chapter 21 Solutions
Chemistry with Access Code, Hybrid Edition
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- Specify whether the following complexes have isomers.. (a) tetrahedral [Ni(CO)2(Cl)2]. (b) trigonal bipyramidal [Mn(CO)4NO]. (c) [Pt(en)2Cl2]Cl2arrow_forwardWhat two first-row transition metals have unexpected electron configurations? A statement in the text says that first-row transition metal ions do not have 4s electrons. Why not? Why do transition metal ions often have several oxidation states, whereas representative metals generally have only one?arrow_forwardWhich of the following species is most paramagnetic? (a) Cr (b) Cr3+ (c) Mn (d) Mn2+arrow_forward
- Name the following complexes, using IUPAC rules. a K4[Mo(CN)8] b [CrF6]3 c [V(C2O4)3]2 d K2[FeCl4]arrow_forwardExperiments show that K4[Cr(CN)6] is paramagnetic and has two unpaired electrons. The related complex K4[Cr(SCN)6] is paramagnetic and has four unpaired electrons. Account for the magnetism of each compound using the ligand field model. Predict where the SCN ion occurs in the spectro-chemical series relative to CN.arrow_forwardThe complex ion NiCL42 has two unpaired electrons, whereas Ni(CN)42 is diamagnetic. Propose structures for these two complex ions.arrow_forward
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