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Concept explainers
(a)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
(b)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
(c)
Interpretation:
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.
Concept introduction:
The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.
The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.
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Chapter 21 Solutions
Chemistry with Access Code, Hybrid Edition
- Nonearrow_forwardTransmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)arrow_forwardNonearrow_forward
- Draw the Lewis structure of C2H4Oarrow_forwarda) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 productarrow_forwardNonearrow_forward
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