Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 21, Problem 49E
Write the two-resonance structures for the acetate ion.
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 21 Solutions
Chemistry Atoms First2e
Ch. 21 - Write the chemical formula and Lewis structure of...Ch. 21 - What is the difference between the hybridization...Ch. 21 - On a microscopic level, how does the reaction of...Ch. 21 - On a microscopic level, how does the reaction of...Ch. 21 - Explain why unbranched alkenes can form geometric...Ch. 21 - Explain why these two molecules are not isomers:Ch. 21 - Explain why these two molecules are not isomers:Ch. 21 - How does the carbon-atom hybridization change when...Ch. 21 - Write the Lewis structure and molecular formula...Ch. 21 - Write the chemical formula, condensed formula, and...
Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Butane is used as a fuel in disposable lighters....Ch. 21 - Write Lewis structures and name the five...Ch. 21 - Write Lewis structures for the Cis -trans isomers...Ch. 21 - Write structures for the three isomers of the...Ch. 21 - Isooctane is the common name of the isomer of...Ch. 21 - Write Lewis structures and IUPAC names for the...Ch. 21 - Write Lewis structures and IUPAC names for all...Ch. 21 - Name and write the structures of all isomers of...Ch. 21 - Write the structures for all the isomers of the...Ch. 21 - Write Lewis structures and describe the molecular...Ch. 21 - Benzene is one of the compounds used as an octane...Ch. 21 - Teflon is prepared by the polymerization of...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - What mass of 2-bromopropane could be prepared from...Ch. 21 - Acetylene is a very weak acid; however, it will...Ch. 21 - Ethylene can be produced by the pyrolysis of...Ch. 21 - Why do the compounds hexane, hexanol, and hexane...Ch. 21 - Write condensed formulas and provide IUPAC names...Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Give the complete IUPAC name and the common name...Ch. 21 - Write the condensed structures of both isomers...Ch. 21 - Write the condensed structures of all isomers with...Ch. 21 - Draw the condensed formulas for each of the...Ch. 21 - MTBE, Methyl tert -butyl ether, CH3OC(CH3)3, is...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Order the following molecules from least to most...Ch. 21 - Predict the products of oxidizing the molecules...Ch. 21 - Predict the products of reducing the following...Ch. 21 - Explain why it is not possible to possible a...Ch. 21 - How does hybridization of the substituted carbon...Ch. 21 - Fatty acids are carboxylic acids that have long...Ch. 21 - Write a condensed structural formula, such as...Ch. 21 - Write a condensed structural formula, such as...Ch. 21 - The foul odor of rancid butter is caused by...Ch. 21 - Write the two-resonance structures for the acetate...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Yields in organic reactions are sometimes low....Ch. 21 - Alcohols A, B and C all have the composition C4H...Ch. 21 - Write the Lewis structures of both isomers with...Ch. 21 - What is the molecular structure about the nitrogen...Ch. 21 - Write the two resonance structures for the...Ch. 21 - Draw Lewis structures for pyridine and its...Ch. 21 - Write the Lewis structures of all isomers with the...Ch. 21 - Write two complete balanced equations for the...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Identify any carbon atoms that change...Ch. 21 - Identify any carbon atoms that change...Ch. 21 - Identify any carbon atoms that change...
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- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
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- CHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the limiting or determining step approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.arrow_forwardTRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forward
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